Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals

Khalil Khalaf Abid

doi:doi:10.11648/j.ajac.20130105.12

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Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals

Khalil Khalaf Abid

Published in American Journal of Applied Chemistry (Volume 1, Issue 5)

Received: 28 October 2013 Accepted: Published: 10 December 2013

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Abstract

Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.

Published in	American Journal of Applied Chemistry (Volume 1, Issue 5)
DOI	10.11648/j.ajac.20130105.12
Page(s)	87-91
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Lanthanides, Schiff Bases, 2, 6-Diformyl Phenol, Pentadentate Acyclic Ligand

References

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Khalil Khalaf Abid. (2013). Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. American Journal of Applied Chemistry, 1(5), 87-91. https://doi.org/10.11648/j.ajac.20130105.12

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ACS Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am. J. Appl. Chem. 2013, 1(5), 87-91. doi: 10.11648/j.ajac.20130105.12

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AMA Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am J Appl Chem. 2013;1(5):87-91. doi: 10.11648/j.ajac.20130105.12

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@article{10.11648/j.ajac.20130105.12,
  author = {Khalil Khalaf Abid},
  title = {Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {5},
  pages = {87-91},
  doi = {10.11648/j.ajac.20130105.12},
  url = {https://doi.org/10.11648/j.ajac.20130105.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130105.12},
  abstract = {Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.},
 year = {2013}
}

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TY  - JOUR
T1  - Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals
AU  - Khalil Khalaf Abid
Y1  - 2013/12/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130105.12
DO  - 10.11648/j.ajac.20130105.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 87
EP  - 91
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130105.12
AB  - Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.
VL  - 1
IS  - 5
ER  -

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Author Information

Khalil Khalaf Abid

Department of Chemistry, College of Science, Al – Mustansiryah University 10052 Baghdad – Iraq

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APA Style

Khalil Khalaf Abid. (2013). Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. American Journal of Applied Chemistry, 1(5), 87-91. https://doi.org/10.11648/j.ajac.20130105.12

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ACS Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am. J. Appl. Chem. 2013, 1(5), 87-91. doi: 10.11648/j.ajac.20130105.12

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AMA Style

Khalil Khalaf Abid. Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals. Am J Appl Chem. 2013;1(5):87-91. doi: 10.11648/j.ajac.20130105.12

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@article{10.11648/j.ajac.20130105.12,
  author = {Khalil Khalaf Abid},
  title = {Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {5},
  pages = {87-91},
  doi = {10.11648/j.ajac.20130105.12},
  url = {https://doi.org/10.11648/j.ajac.20130105.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130105.12},
  abstract = {Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals
AU  - Khalil Khalaf Abid
Y1  - 2013/12/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130105.12
DO  - 10.11648/j.ajac.20130105.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 87
EP  - 91
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130105.12
AB  - Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.
VL  - 1
IS  - 5
ER  -

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