The main goal of this study is to evaluate the potential for glyphosate to contaminate water and ground water. For this purpose, the adsorption of glyphosate on a soil of culture in West of Côte d’Ivoire is investigated. The chemical composition of the soil, the different materials that compose it as well as the pH of zero charge of this soil were determined. The results revealed that the soil sample was rich in iron oxide mainly goethite, phengite and anatase. Adsorption kinetics was studied and the rate of sorption was found to conform to pseudo-second-order kinetics with 90 min as equilibrium time. Equilibrium isotherm data were analyzed according to Langmuir and Freundlich models. The two models describe the adsorption phenomenon well. The soil is heterogeneous with a good affinity between the metal oxides of the soil and the glyphosate. The maximum adsorption capacities were determined to be 2.68 mg/g. Parameters such as the initial pH of the solution, the mass of soil and the temperature were well investigated. It is observed that the adsorbed amount of glyphosate increases with temperature, reflecting the endothermic nature of the adsorption. The maximum amount of glyphosate adsorbed at 40°C is approximately 3 mg/g. The amount of glyphosate adsorbed increases with the initial concentration and decreases with the increase of pH. The optimal pH is therefore 5.
| Published in | American Journal of Applied Chemistry (Volume 9, Issue 6) |
| DOI | 10.11648/j.ajac.20210906.15 |
| Page(s) | 213-220 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Pesticides, Iron Oxides, Adsorption Phenomenon, Kinetics, Isotherm, pH
| [1] | Margni M., Rossier D., Crettaz P., Jolliet O. (2002) Life cycle impact assessment of pesticides on human health and ecosystems. Agriculture Ecosystems and Environment, 93, 379-392. |
| [2] | Erol A., Numan H. (2005) Adsorption kinetics and isotherms of pesticides onto activated carbon-cloth. Chemosphere, 60, 1600-1607. |
| [3] | Nourouzi M. M., Chuah T. G., Thomas S. Y. (2010) Adsorption of glyphosate onto activated carbon derived from waste newspaper. Desalination and Water Treatment, 24, 321-326. doi: 10.5004/dwt.2010.1461 |
| [4] | Borggaard O. K., Gimsing A. L. (2008) Fate of glyphosate in soil and the possibility of leaching to ground and surface waters: a review. Pest Management Sciences, 64, 441-456. |
| [5] | Kamalesh S., Jayanta K. D., Naba K. M. (2019) Glyphosate adsorption by Eucalyptus camaldulensis bark-mediated char and optimization through response surface modeling. Applied Water Science, 9 (162), 1-12. |
| [6] | Feng D., Soric A., Boutin O. (2020) Treatment technologies and degradation pathways of glyphosate: A critical review. Science of the Total Environment, 742, 1-14. https://doi.org/10.1016/j.scitotenv.2020.140559 |
| [7] | Andreotti G., Koutros S., Hofmann J. N., Sandler D. P., Lubin J. H., Lynch C. F., Lerro C. C., Roos D., Parks C. G., Alavanja M. C., Silverman D. T., Freeman B. (2018) Glyphosate use and cancer incidence in the agricultural health study. Journal of the National Cancer Institute, 110(5), 509-516. https://doi.org/10.1093/jnci/djx233. |
| [8] | Gimsing A. L., Borggaard O. K. (2007) Phosphate and glyphosate adsorption by hematite and ferrihydrite and comparison with other variable charge minerals. Clays Clay Mineral, 55, 108-114. |
| [9] | Morillo E., Undabeytia T., Maqueda C., Ramos A. (2000) Glyphosate adsorption on soils of different characteristics. Influence of copper addition. Chemosphere, 40, 103-107. |
| [10] | Pereira R. C., Antonio C. S., Flavio F. I., Andrea P. J., Dimas A. M. Z. (2020) Interaction between glyphosate and montmorillonite in the presence of artificial seawater. Heliyon. 6 (3), e03532. https://doi.org/10.1016/j.heliyon.2020.e03532. |
| [11] | Day G. M., Hart B. T., McKelvie I. D., Beckett R. (1997) Infuence of natural organic matter on the sorption of biocides onto goethite. II. Glyphosate. Environment Technology, 18, 781-794. |
| [12] | Castro J. V., Peralba M. C. R., Ayub M. A. Z. (2007) Biodegradation of the herbicide glyphosate by filamentous fungi in platform shaker and batch bioreactor. Journal of Environmental Science and Health Part B, 42, 883-886. https://doi.org/10.1080/03601230701623290. |
| [13] | Ministère de l’Agriculture de Côte D’ivoire- ISYSPHYT.CI. (2012) Liste actualisée des pesticides homologués et autorisés en Côte d’Ivoire 31 Décembre 2012. www.ISYSPHYT.CI |
| [14] | Arlette M., Cardenas P., Jorge G. I., Ruben V. M. (2012) Determination of the Point of Zero Charge for Electrocoagulation Precipitates from an Iron Anode. International Journal of Electrochemistry Science, 7, 6142 – 6153. |
| [15] | Abo E. A., Yobouet Y. A., Kouakou Y. U., Trokourey A. (2020) Optimization of the preparation of activated carbon based on corn cobs and physico-chemical characterization. International Journal of Innovation and Applied, 29 (4), 1161-1171. |
| [16] | Wang S., Zhu Z. H. (2005) The Physical and Surface Chemical Characteristics of Activated Carbons and the Adsorption of Methylene Blue from Wastewater, Journal of Colloid and Interface Science, 284 (2), 440- 446. |
| [17] | Ilina S. M., Ollivier P., Slomberg D., Baran N., Pariat A., Devau N., Sani-Kast N., Scheringer M., Labille J. (2017) Investigations into titanium dioxide nanoparticle and pesticide interactions in aqueous environments. Environmental Science: Nanoscience, 00, 1-3, 1-14. Doi: 10.1039/C7EN00445A. |
| [18] | Dideriksen K., Stipp S. L. S. (2003) The adsorption of glyphosate and phosphate to goethite: A molecular-scale atomic force microscopy study. Geochimica et Cosmochimica Acta., 67 (18), 3313–3327. doi:10.1016/S0016-7037(02)01369-8 |
| [19] | Paszko T. (2006) Sorptive behavior and kinetics of carben-dazim in mineral soils. Polish Journal Environmental Studies, 15 (3), 449-456. |
| [20] | Jensen L. C., Fuentes R., Báez M. E., Escudey M. (2009) Adsorption of Glyphosate on Variable-Charge, Volcanic Ash-Derived Soils. Journal of Environmental Quality, 38, 1449–1457. doi:10.2134/jeq2008.0146 |
| [21] | Hameed B. H., Krishni R. R., Sata S. A. (2009) A novel agricultural waste adsorbent for the removal of cationic dye from aqueous solutions. Journal of Hazardous Material, 162, 305–311 |
| [22] | Orcelli T., Eduardo M., Alexandre U., Valezi D. F., Antonio C. S., Cássia T. B., Zaia D. A. M. (2018) Study of Interaction Between Glyphosate and Goethite Using Several Methodologies: an Environmental Perspective. Water Air Soil Pollution, 229, 150-162. https://doi.org/10.1007/s11270-018-3806-1 |
| [23] | Marco-Brown J. L., Barbosa-Lema C. M., Sánchez R. M. T., Mercader R. C., Afonso M. S. (2012) Adsorption of picloram herbicide on iron oxide pillared montmorillonite. Applied Clay Science, 58, 25-33. doi: 10.1016/j.clay.2012.01.004 |
| [24] | Donald L. S. (2003) Sorption Phenomena on Soils. Environmental Soil Chemistry; Donald, L. S., Eds.; Second Edition: Academic Press, 133-186. |
| [25] | Clausen L., Fabricius I. (2001) Atrazine, isoproturon, mecoprop, 2,4-D, and bentazone adsorption onto iron oxides. Journal of Environmental Quality 30(3), 858-869. doi: 10.2134/jeq2001.303858x. |
| [26] | Li F., Wang Y., Yang Q., Evans D. G., Forano C., Duan X. (2005) Study on adsorption of glyphosate (N-phosphonomethyl glycine) pesticide on MgAl-layered double hydroxides in aqueous solution. Journal of Hazardous Material 125, 89–95. https://doi.org/10.1016/j.jhazmat.2005.04.037. |
| [27] | Villa M. V., Sánchez-Martín M. J., Sánchez-Camazano M. (1999) Hydrotalcites and organohydrotalcites as sorbents for removing pesticides from water. Journal of Environmental Science and Health Part B, 34, 509–525. https://doi.org/10.1080/03601239909373211 |
| [28] | Accinelli C., Koskinen W., Seebinger J. D., Vicari A., Sadowsky M. (2005) Effects of incorporated corn residues on glyphosate mineralization and sorption in soil. Journal of Agricultural and Food Chemistry, p 53. |
| [29] | Taha H. (2014) Etude de l’adsorption du COS sur des oxydes métalliques: influence des propriétés acido-basiques de surface et des compétitions d’adsorption COS-CO2-H2S. Matériaux. Université Pierre et Marie Curie - Paris VI, Français. ffNNT: 2014PA066243ff. Fftel-01086574f. |
APA Style
Kouakou Yao Urbain, Kambiré Ollo, Kouakou Kpan Kpan Gains, Trokourey Albert. (2021). Study of Potential Adsorption of Glyphosate on Iron-textured Soil. American Journal of Applied Chemistry, 9(6), 213-220. https://doi.org/10.11648/j.ajac.20210906.15
ACS Style
Kouakou Yao Urbain; Kambiré Ollo; Kouakou Kpan Kpan Gains; Trokourey Albert. Study of Potential Adsorption of Glyphosate on Iron-textured Soil. Am. J. Appl. Chem. 2021, 9(6), 213-220. doi: 10.11648/j.ajac.20210906.15
AMA Style
Kouakou Yao Urbain, Kambiré Ollo, Kouakou Kpan Kpan Gains, Trokourey Albert. Study of Potential Adsorption of Glyphosate on Iron-textured Soil. Am J Appl Chem. 2021;9(6):213-220. doi: 10.11648/j.ajac.20210906.15
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Download@article{10.11648/j.ajac.20210906.15,
author = {Kouakou Yao Urbain and Kambiré Ollo and Kouakou Kpan Kpan Gains and Trokourey Albert},
title = {Study of Potential Adsorption of Glyphosate on Iron-textured Soil},
journal = {American Journal of Applied Chemistry},
volume = {9},
number = {6},
pages = {213-220},
doi = {10.11648/j.ajac.20210906.15},
url = {https://doi.org/10.11648/j.ajac.20210906.15},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20210906.15},
abstract = {The main goal of this study is to evaluate the potential for glyphosate to contaminate water and ground water. For this purpose, the adsorption of glyphosate on a soil of culture in West of Côte d’Ivoire is investigated. The chemical composition of the soil, the different materials that compose it as well as the pH of zero charge of this soil were determined. The results revealed that the soil sample was rich in iron oxide mainly goethite, phengite and anatase. Adsorption kinetics was studied and the rate of sorption was found to conform to pseudo-second-order kinetics with 90 min as equilibrium time. Equilibrium isotherm data were analyzed according to Langmuir and Freundlich models. The two models describe the adsorption phenomenon well. The soil is heterogeneous with a good affinity between the metal oxides of the soil and the glyphosate. The maximum adsorption capacities were determined to be 2.68 mg/g. Parameters such as the initial pH of the solution, the mass of soil and the temperature were well investigated. It is observed that the adsorbed amount of glyphosate increases with temperature, reflecting the endothermic nature of the adsorption. The maximum amount of glyphosate adsorbed at 40°C is approximately 3 mg/g. The amount of glyphosate adsorbed increases with the initial concentration and decreases with the increase of pH. The optimal pH is therefore 5.},
year = {2021}
}
TY - JOUR T1 - Study of Potential Adsorption of Glyphosate on Iron-textured Soil AU - Kouakou Yao Urbain AU - Kambiré Ollo AU - Kouakou Kpan Kpan Gains AU - Trokourey Albert Y1 - 2021/12/31 PY - 2021 N1 - https://doi.org/10.11648/j.ajac.20210906.15 DO - 10.11648/j.ajac.20210906.15 T2 - American Journal of Applied Chemistry JF - American Journal of Applied Chemistry JO - American Journal of Applied Chemistry SP - 213 EP - 220 PB - Science Publishing Group SN - 2330-8745 UR - https://doi.org/10.11648/j.ajac.20210906.15 AB - The main goal of this study is to evaluate the potential for glyphosate to contaminate water and ground water. For this purpose, the adsorption of glyphosate on a soil of culture in West of Côte d’Ivoire is investigated. The chemical composition of the soil, the different materials that compose it as well as the pH of zero charge of this soil were determined. The results revealed that the soil sample was rich in iron oxide mainly goethite, phengite and anatase. Adsorption kinetics was studied and the rate of sorption was found to conform to pseudo-second-order kinetics with 90 min as equilibrium time. Equilibrium isotherm data were analyzed according to Langmuir and Freundlich models. The two models describe the adsorption phenomenon well. The soil is heterogeneous with a good affinity between the metal oxides of the soil and the glyphosate. The maximum adsorption capacities were determined to be 2.68 mg/g. Parameters such as the initial pH of the solution, the mass of soil and the temperature were well investigated. It is observed that the adsorbed amount of glyphosate increases with temperature, reflecting the endothermic nature of the adsorption. The maximum amount of glyphosate adsorbed at 40°C is approximately 3 mg/g. The amount of glyphosate adsorbed increases with the initial concentration and decreases with the increase of pH. The optimal pH is therefore 5. VL - 9 IS - 6 ER -
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