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Ranges and Fitting Ratios of Natural Aggregates for a Sustainable and Effective Fe°/Sand/Pozzolan Ternary Device Using Orange Methyl

Received: 24 January 2022    Accepted: 10 February 2022    Published: 25 February 2022
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Abstract

The remediation effectiveness of a Fe°/Sand/Pozzolan (Fe°/S/Pz) ternary device using an azo-dye for characterization is demonstrated herein. Optimal operating conditions, which specify the proportions of solid materials, such as iron (Fe°), sand (S), and pozzolan (Pz), in the reactive zone (RZ), are essential factors for the performance of such heterogeneous devices. Thus, the operative indicator orange methyl (OM) of 2 mg/L was used. Performance parameters such as pH, released iron of the collected water, flow rate, and fading power were measured using filter devices containing (1) 100% Fe°, (2) 25%/75% Fe°/S, (3) 25%/75% Fe°/Pz, (4) 25%/0%/75% Fe°/S/Pz, (5) 25%/25%/50% Fe°/S/Pz and (6) 25%/50%/25% Fe°/S/Pz for a correlation of proportions, reactivity, and performance. The experiments lasted thirty (30) days per device. It turns out that ranges of 25% ≤ % Fe° ≤ 60%, 25% ≤ %S ≤ 50%, and 25% ≤ %Pz ≤ 50% are quite enough. The ternary device, in ratios of 25%/50%/25% Fe°/S/PZ, is an excellent decontaminant of orange methyl OM, with regulation of pH and residual iron levels, for acceptable flows. There are therefore beneficial effects of the association of a non-expansive porous material with Fe°-based filters to delay clogging by collecting corrosion products (CPs). 25%/50%/25% Fe°/S/PZ device allow to reduce greatly the proportion of iron in the reactive zone (RZ) since pure iron devices are not recommended due to clogging. 25% ≤ % Fe° ≤ 60%, 25% ≤ %S ≤ 50%, and 25% ≤ %Pz ≤ 50% could provide a necessary framework for all Fe°-bed filters.

Published in American Journal of Applied Chemistry (Volume 10, Issue 1)
DOI 10.11648/j.ajac.20221001.13
Page(s) 15-27
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Aqueous Corrosion, Fe°-bed Filters, Orange Methyl, Pozzolan, Ratio, Sand, Zero-valent Iron

References
[1] Begum, A., & Harikrishna, S. (2009). Analysis of heavy metals in water, sediments and fish samples of Madivala lakes of Bangalore, Karnataka. Chem. Tech. 1: 245.
[2] Ndé-Tchoupé, A. I., Makota, S., Nassi, A., Rui, H., & Noubactep, C. (2018). The suitability of pozzolan as admixing aggregate for Fe°-Based Filters. Water 10: 417.
[3] Ngai, T. K. K., Shrestha, R. R., Dangol, B., Maharjan, M., & Murcott, S. E. (2007). Design for sustainable development - Household drinking water filter for Arsenic and pathogen treatment in Nepal. J. Environ. Sci. Health 42: 1879-1888.
[4] Munir, A. K. M., Rasul, S. B., Habibuddowla, M, Hussam, A., & Khan, A. H. (2001). Evaluation of performance of filter for arsenic removal from groundwater using zero-valent iron through laboratory and field studies. Technologies for arsenic removal from drinking water. 171 – 189.
[5] Hussam, A., & Munir, A. K. M. (2007). A simple and effective arsenic filter based on Composite iron matrix: Development and deployment studies for groundwater of Bangladesh. J. Environ. Sci. Health 42: 1869-1878.
[6] Neumann, A., Kaegi, R., Voegelin, A., Hussam, A., Munir, A. K. M., & Hug, S. J. (2013). Arsenic removal with composite iron matrix filters in Bangladesh: a field and laboratory study. Environ. Sci. Technol. 47: 4544-4554.
[7] Chiew, H., Sampson, M. L., Huch, S., & Bostick, B. C. (2009). Effect of groundwater iron and phosphate on the efficacy of arsenic removal by Iron-amended Bio Sand Filters, Environ. Sci. Technol. 43: 6295 – 6300.
[8] Ngai, T. K. K., Murcot, S., Shrestha, R. R., Dangol, B., & Maharjan, (2006). M. Development and dissemination of KanchanTM arsenic filter in rural Nepal. Water Sci. Technol. Water Supply 6: 137-146.
[9] Li, S.; Heijman, S., Verberk, J., & Van Dijk, J. (2009). An innovative treatment concept for future drinking water production: Fluidized ion exchange – Ultrafiltration nanofiltration – Granular activated carbon filtration, Drink. Water Eng. Sci. 2: 41–47.
[10] Nasseri, E., Ndé-Tchoupé, A. I., Mwakabona, H. T., Nanseu-Njiki, C. P., Noubactep, C., Njau, K. N., & Wydra, K. D. (2017). Making Fe°-based filters a universal solution for safe drinking water provision. Sustainability 9: 1224.
[11] Noubactep, C. (2009). An analysis of the evolution of reactive species in Fe°/H2O systems. J. Hazard Mater 168: 1626- 1631.
[12] Ebelle, T. C., Makota, S., Tepong-Tsindé, R., Nassi, A., & Noubactep, C. August (2016). Metallic iron and the dialogue of the deaf. Fres. Environ. Bull. 28 (11A): 8331-8340.
[13] Makota, S., Ndé-Tchoupé, A. I., Mwakabona, H. T., Tepong-Tsindé, R., Noubactep, C., Nassi, A., & Njau, K. N. (2017). Metallic iron for water treatment: leaving valley of confusion. Appl. Water Sci. 7: 4177-4196.
[14] Noubactep, C., Makota, S., & Randyopadhyay, A. (2017). Rescuing Fe° remediation research from its systemic flaws. Res. Rev. Insights 1 (4): 1-8.
[15] Kumar, R., & Sinha, A. (2017). Biphasic reduction model for predicting the impacts of dye-bath constituents on the reduction of tris - azo dye Direct Green-1 by zero-valent (Fe°). J. Environ. Sci. (China) 52: 160-169.
[16] Guan, X., Sun, Y., Qin, H., Li, J., Lo, I. M. C., He, D., & Dong, H. (2015). The limitations of applying zero-valent iron technology in contaminants sequestration and the corresponding countermeasures: The development in zero-valent iron technology in the last two decades (1994-2014). Water Res. 75: 224-248.
[17] Guo, X., Yang, Z., Dong, H., Guan, X., Run, Q., Lv, X., & Jin, X. (2016). Simple combination of oxidants with zero-valent- iron (ZVI) achieved very rapid and highly efficient removal of heavy metals from water.. Water Res. 88: 671- 680.
[18] Gillham, R. W., & O’Hannesin, S. F. (1994). Enhance degradation of halogenated aliphatic by zero-valent iron. Ground Water 32: 958-967.
[19] O’Hannesin, S. F., & Gillham, R. W. (1998). Long-term performance of an in situ “iron wall” for remediation of VOCs. Ground Water 36: 164-170.
[20] Andersen, M. A. (1989). Fundamental aspects of selenium removal by Harza process. Rep San Joaquin Valley Drainage Program, US Dep. Interior, Sacramento.
[21] Gillham, R. W. (2010). Development of the granular iron permeable reactive barrier technology (good science or good fortune) In “Advances environmental geotechnics: proceedings of the International Symposium on Geoenvironmental Engineering in Hangzhou, China, September (2009)”, 8-10; Chen, Y.; Tang, L.; Zhan (Eds); Springer Berlin/London, pp 5-15.
[22] Diao, M., & Yao, M. (2009). Use of zero-valent iron nanoparticles in inactivating microbes, Water Res. 43: 5243–5251.
[23] Casentini, B., Falcione, F. T., Amalfitano, S., Fazi, S., & Rossetti, S. (2016). Arsenic removal by discontinuous ZVI two steps system for drinking water production at household scale. Water Res. 106: 135-145.
[24] Smith, K., Li, Z., Chen, B., Liang, H., Zhang, X., Li, Z., Dai, H., Wei, C., & Liu, S. (2017). Comparison of sand-based water filters for point-of-use arsenic removal in China. Chemosphere 168: 155-162.
[25] Anderson, W. (1885). The purification of water by means of iron on the large scale. Minutes of the Proceedings of the Institution of Civil Engineers 81: 279-284.
[26] Henderson, A. D., & Demond, A. H. (2007). Long-term performance of zero-valent iron permeable reactive barriers: a critical review. Environ. Eng. Sci. 24: 401-423.
[27] Comba, S., Di Molfetta, A., Sethi, R. (2011). A comparison between field applications of nano-, micro-, and millimetric zero-valent iron for the remediation of contaminated aquifers. Water Air Soil Pollut. 215: 595-607.
[28] Gheju M. (2011). Hexavalent chromium reduction with zero-valent iron (ZVI) in aquatic systems Water Air Soil Pollut. 222: 103-148.
[29] Detay, M. (1993). Le forage de l’eau. Ingénierie de l’environnement p. 231-242, (Eds) Masson (In French).
[30] Noubactep, C. (2010a). The fundamental mechanism of aqueous contaminant removal by metallic iron. Water SA 36, 663-670.
[31] Lamoureux, J-J. (2000). Précis de corrosion. Sciences des matériaux p. 1-78, (2e Eds) Masson.
[32] Noubactep, C. (2006). Contaminant reduction at the surface of elemental iron: The end of a myth. Wissenschaftliche Mitteilungen Freiberg 31: 173-179.
[33] Noubactep, C. (2007). Processes of contaminant removal in ‘’Fe°-H2O’’ systems revisited: The importance of co-precipitation. Open Environ. Sci. 1: 9-13.
[34] Noubactep, C. (2008). Processes of contaminant removal in ‘’Fe°-H2O’’ systems revisited: The importance of co-precipitation. Open Environ. Sci. 1: 9-13.
[35] Nesic, S. (2007). Key issues related to modeling of internal corrosion of oil and gas pipelines –A review: Corros. Sci. 49: 4308-4338.
[36] Odziemkowski, M. S., & Simpraga, R. P. (2004). Distribution of oxides on iron materials used for remediation of organic groundwater contaminants-Implications for hydrogen evolution reactions. Can. J. Chem 82: 1495-1506.
[37] Bischof, G. (1877). On putrescent organic matter in potable water I. Proceedings of the Royal Society of London 26: 179-184.
[38] Baker, M. (1934). Sketch of the history of water treatment. Journal American Water Works Association 26: 902-938.
[39] Noubactep, C. (2016b). Designing metallic iron packed-beds for water treatment: A critical review Clean- Soil, Air, Water 44: 411-421.
[40] Ghauch, A. (2015). Iron-based metallic systems: An excellent choice for sustainable water treatment. Freiberg Online Geosci. 38: p. 80.
[41] Keenan, C., & Salad, D. L. (2008). Factors affecting the yield of oxidants from the reaction of nanoparticulate zero-valent iron and oxygen. Environ. Sci. Technol. 42: 1262-1267.
[42] Pilling, N. B., &Bedworth, R. E. The oxidation of metals at high temperatures. J. Inst. Metals (1923). 29: 529, 591.
[43] Crawford, R. J., Harding, I. H., & Mainwaring, D. E. (1993a). Adsorption and coprecipitation of single heavy metal ions onto the hydrated oxides of iron and chromium. Langmuir 9: 3050-3056.
[44] Crawford, R. J., Harding, I. H., Mainwaring, D. E. (1993a). Adsorption and co precipitation of multiple heavy metal ions onto the hydrated oxides of iron and chromium. Langmuir 9: 3057-3062.
[45] Schwertmann, U. (1991). Solubility and dissolution of iron oxides. Plants and Soil 130: 1-25.
[46] Brown Jr, G. E., Henrich, V. E., Casey, W. H., Clark, D. L., Eggleston, C., Felmy, A., Googman, D. W., Grātzel, M., Maciel, G., McCarthy, M. I., Nealson, K. H., Sverjensky, D. A., Toney, M. F., & Zachara, J. M. (1999). Metal oxide surfaces and their interactions with aqueous solutions and microbial organisms. Chem. Rev. 99: 77-174.
[47] Detay, M. (1993). Le forage de l’eau. Ingénierie de l’environnement p. 250-259, (Eds) Masson (In French).
[48] Lazzari, L. (2008). General aspects of corrosion, chapter 9.1: vol. V, Encyclopedia of hydrocarbons, Istituto Enciclopedia Italiana, Rome, Italy.
[49] Makenzie, P. D. I., Horney, D. P., & Sivavec, T. M. (1999). Mineral precipitation and porosity losses in granular in granular iron columns. J Hazard Mater 68: 1-17.
[50] Li, L., & Benson, C. H. (2010). Evaluation of five strategies to limit the impact of fouling in permeable reactive barriers. J. Hazard Mater 181: 170-180.
[51] Moore, A., & Young, T. (2005). Chloride interactions with iron surfaces: Implications for perchlorate and nitrate remediation using permeable reactive barriers. J. Environ. Eng. 131: 924-933.
[52] Phukan, M. (2015). Characterizing the Fe°/sand system by the extent of dye discoloration. Freiberg Online Geosci. 40: 70.
[53] Gatcha-Bandjun, N., Noubactep, C., & Loura Mbenguela, B. (2017). Mitigation of contamination in effluents by metallic iron: The role of iron corrosion products. Environ. Technol. Innov. 8: 71-83.
[54] Noubactep, C. (2013a). Relevant reducing agents in remediation Fe°/H2O systems Clean-Soil Air Water 41: 493-502.
[55] Miyajima, K. (2012). Optimizing the design of metallic iron filters for water treatment. Freiberg Online Geosci. 32: 107.
[56] Yao, K. M., Habibian, M. T., & O’melia, C. R. (1971). Water and waste water filtration: concepts and applications. Environ. Sci. Technol. 5: 1105-1112.
[57] Howe, K. J., Hand, D. W., Crittenden, J. C., Trussel, R. R., Tchobanoglous, G. (2012). Principles of water treatment. John & Wiley Sons, Inc., Hoboken, New Jersey, 674.
[58] Seng, C. L., Yang, M. H., &Lin, C. C. (1984). Rapid determination of cobalt-60 in sea water with steel wool adsorption. J. Radioanal. Nuclu. Chem. Lett. 85: 253-260.
[59] James, B. R., Rabenhorst, M. C., & Frigon, G. A. (1992). Phosphorus sorption by peat and sand amended with iron oxides or steel wool. Water Environ. Res 64, 699-705.
[60] Bischof, G. (1878). On putrescent organic matter in potable water. II. Proceedings of the Royal Society of London 27: 258-261.
[61] Lackovic, J. A., Nikolaidis, N. P., & Dobbs, G. M. (2000). Inorganic arsenic removal by zero-valent iron. Environ. Eng. Sci. 17: 29-39.
[62] Noubactep, C. (2010b). Metallic iron for safe drinking water worldwide. Chem. Eng. J. 165: 740-749.
[63] Noubactep, C. (2012). Investigating the processes of contaminant removal in Fe°/H2O systems. Korean J. Chem. Eng. 29: 1050-1056.
[64] Noubactep, C. (2011b). Metallic iron for safe drinking water production. Freiberg Online Geosci. 27: p. 38.
[65] Luo, P., Bailey, E. H., Mooney, S. J. (2013). Quantification of changes in zero valent iron morphology using X-ray computed tomography. J. Environ. Sci. 25 (11): 2344-2351.
[66] Ndé-Tchoupé, A. I. Crane, R. A., Mwakabona, H. T., Noubactep, C., & Njau, K. (2015). Technologies for decentralized fluoride removal: Testing metallic iron -based filters. Walter 7: 6750-6774.
[67] Tepong-Tsindé, R., Crane R., Noubactep, C., Nassi, A., & Ruppert, H. (2015). Testing metallic iron filtration systems for decentralized water treatment at pilot scale. Water 7: 868-897.
[68] Noubactep, C. (2016a). Predicting the hydraulic conductivity of metallic iron filters: Modeling gone astray. Water 162.
[69] Harza Engineering Co. (1986). Selenium removal study, Report to Panoche Drainage District. Harza Engineering Co., Firebaugh, California, USA.
[70] Rahman, M. A., Karmakar, S., Salama, H., Gactha-Bandjun, N., Btatkeu-K, B. D., & Noubactep, C. (2013). Optimising the design of FeO-based filtration systems for water treatment: The suitability of porous iron composites. J. Appl. Solut. Chem. Model. 2: 165–177.
[71] Iler, R. (1979). The Chemistry of Silica. Wiley Intersci. Public. 35 pp. New York, USA.
[72] Miyajima, K., & Noubactep, C. (2012). Effects of Mixing Granular Iron with Sand on the Efficiency of Methylene Blue Discoloration. Chem. Eng. J433–438.
[73] Wilkin, R., Puls, R., & Sewell, G. (2003). Long-term performance of permeable reactive barriers using zero-valent iron: geochemical and microbiological effects, Ground Water 41: 493-503.
[74] Itchell, G., Poole, P., Segrove, H. (1955). Adsorption of Methylene Blue by High-Silica Sands. Nature 176: 1025-1026.
[75] Dron, R. (1975). Les pouzzolanes et la pouzzolanicité. Revue des matériaux de construction (In French). N° 692: 27-30.
[76] Kofa, G. P., NdiKoungou, S., Kayem, G. J., Kamga, R. (2015). Adsorption of arsenic by natural pozzolan in a fixed bed: determination of operating conditions and modeling. J. Water Process Eng. 6: 166–173.
[77] Billong, N., Chinje Melo U., Njopwouo, D., Louvet, F., & Bonnet, J. P. (2013). Physicochemical characteristics of some Cameroonian pozzolans for use in sustainable cement like materials. Materials Sci. Appl. 4: 14–21.
[78] Sieliechi, J. M., Lartiges, B. S., Ndi, S. K, Kamga, R., & Kayem, G. J. (2012). Mobilization of heavy metal from natural pozzolan by humic acid: implications for water and environment, Int. J Environ. 2, 11-15.
[79] Rocher, P. (1992). Mémento roches et minéraux industriels. Ponces et pouzzolanes. Rapport BRGM, R 36447: 21-22, 45.
[80] Chen, Z. X., Jin, X. Y., Chen, Z. L., Megharaj, M., & Naidu, R. (2011). Removal of methyle orange from aqueous solution using bentonite-supported nanoscale Zero-Valent Iron. J. Colloid. Interf. Sci. 363: 601–607.
[81] Al-heetimi, D.; Dawood, A., Khalaf, Q., & Himdan, T. (2012). Removal of methyle orange from aqueous solutions by Iraqi bentonite adsorbent, Ibn Al-Haitham J. for Pure and Appl. Sci. 1, Vol. 25.
[82] Btatkeu, K., Miyajima, K., Noubactep, C., & Caré, S. (2013). Testing the suitability of metallic iron for environmental remediation: discoloration of methylene blue in column studies. Chem. Eng. J. 215-216, 959–968.
[83] Btatkeu-K, B. D., Olvera-Vargas, H., Tchatchueng, J. B., Noubactep, C., & Caré, S. (2014). Determining the optimum Fe° ratio for sustainable granular Fe°/sand water filters. Chem. Eng. J. 247: 265–274.
[84] Bilardi, S., Calabrò, P. S., Caré, S., Moraci, N., & Noubactep, C. (2013a). Improving the sustainability of granular iron/pumice systems for water treatment. J. Environ. Manag. 121: 133-141.
[85] Bilardi, S., Calabrò, P. S., Caré, S., Moraci, N., & Noubactep, C. (2013b). Effect of pumice and sand on the sustainability of granular iron beds for the removal of CuII, NiII, and ZnII. Clean-Soil Air Water 41: 835-843.
[86] Fortune, W. B., Mellon, M. G. (1938). Determination of iron with o-phenanthroline: A spectrophotometric study. Ind. Eng. Chem. Anal. Ed. 10: 60-64.
[87] Norme NF T 90-017. (1982). Dosage du fer, Méthode spectrométrique à la phénanthroline-1, 10, AFNOR Paris (In French).
[88] Standard Methods for the examination of water, 19th edition, sheet 3-68.
[89] Noubactep, C. (2009). Characterizing the discoloration of methylene blue in Fe°/H2O systems. J. Hazard. Mater. 166: 79-87.
[90] Anderson, W. (1886). On the purification of water by agitation with iron and by sand filtration. Journal of the Society for Arts 35 (1775): 29-38.
[91] Devonshire, E. (1890). The purification of water by means of metallic iron. Journal of the Franklin Institute 129: 449-461.
[92] Visscher, J. T., Paramasivam, R., Raman, A., & Heijnen, H. A. (1991). (IRC) International Water and Sanitation Center / Slow filtration on sand for drinking water supply (In French) pp 51.
[93] Rejsek, F. (2002). Analyse des eaux - Aspects réglementaires et techniques pp 66 (In French).
[94] Bedabrata, S., Sourav, D., Jiban, S., & Gopal, D. (2011). Preferential and Enhanced Adsorption of Different Dyes on Iron Oxide Nanoparticles: A Comparative Study. J. Phys. Chem. C 115: 8024-8033.
[95] Noubactep, C. (2010). Metallic iron for safe drinking waters worldwide. Chem. Eng. J. 165: 740-749.
[96] Kaplan, D. I., & Gilmore, T. J. (2004). Zero-valent iron removal rates of aqueous Cr (VI) measured under flow conditions. Water Air Soil Pollut. 55: 21-33.
[97] Noubactep, C., & Caré, S. (2010). Dimensioning metallic iron beds for efficient contaminant removal. Chem. Eng. J. 163: 454–460.
[98] Noubactep, C., Caré, S., Togue-Kamga, F., Schöner, A., & Woafo, P. (2010). Extending service life of household water filters by mixing metallic iron with sand. Clean – Soil, Air, Water 38: 951-959.
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    Suzanne Makota S. N., Nguemo Wekam Eleonore Armele, Dipita Kolye Ernest Yves Herliche, Nassi Achille. (2022). Ranges and Fitting Ratios of Natural Aggregates for a Sustainable and Effective Fe°/Sand/Pozzolan Ternary Device Using Orange Methyl. American Journal of Applied Chemistry, 10(1), 15-27. https://doi.org/10.11648/j.ajac.20221001.13

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    Suzanne Makota S. N.; Nguemo Wekam Eleonore Armele; Dipita Kolye Ernest Yves Herliche; Nassi Achille. Ranges and Fitting Ratios of Natural Aggregates for a Sustainable and Effective Fe°/Sand/Pozzolan Ternary Device Using Orange Methyl. Am. J. Appl. Chem. 2022, 10(1), 15-27. doi: 10.11648/j.ajac.20221001.13

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    Suzanne Makota S. N., Nguemo Wekam Eleonore Armele, Dipita Kolye Ernest Yves Herliche, Nassi Achille. Ranges and Fitting Ratios of Natural Aggregates for a Sustainable and Effective Fe°/Sand/Pozzolan Ternary Device Using Orange Methyl. Am J Appl Chem. 2022;10(1):15-27. doi: 10.11648/j.ajac.20221001.13

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  • @article{10.11648/j.ajac.20221001.13,
      author = {Suzanne Makota S. N. and Nguemo Wekam Eleonore Armele and Dipita Kolye Ernest Yves Herliche and Nassi Achille},
      title = {Ranges and Fitting Ratios of Natural Aggregates for a Sustainable and Effective Fe°/Sand/Pozzolan Ternary Device Using Orange Methyl},
      journal = {American Journal of Applied Chemistry},
      volume = {10},
      number = {1},
      pages = {15-27},
      doi = {10.11648/j.ajac.20221001.13},
      url = {https://doi.org/10.11648/j.ajac.20221001.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20221001.13},
      abstract = {The remediation effectiveness of a Fe°/Sand/Pozzolan (Fe°/S/Pz) ternary device using an azo-dye for characterization is demonstrated herein. Optimal operating conditions, which specify the proportions of solid materials, such as iron (Fe°), sand (S), and pozzolan (Pz), in the reactive zone (RZ), are essential factors for the performance of such heterogeneous devices. Thus, the operative indicator orange methyl (OM) of 2 mg/L was used. Performance parameters such as pH, released iron of the collected water, flow rate, and fading power were measured using filter devices containing (1) 100% Fe°, (2) 25%/75% Fe°/S, (3) 25%/75% Fe°/Pz, (4) 25%/0%/75% Fe°/S/Pz, (5) 25%/25%/50% Fe°/S/Pz and (6) 25%/50%/25% Fe°/S/Pz for a correlation of proportions, reactivity, and performance. The experiments lasted thirty (30) days per device. It turns out that ranges of 25% ≤ % Fe° ≤ 60%, 25% ≤ %S ≤ 50%, and 25% ≤ %Pz ≤ 50% are quite enough. The ternary device, in ratios of 25%/50%/25% Fe°/S/PZ, is an excellent decontaminant of orange methyl OM, with regulation of pH and residual iron levels, for acceptable flows. There are therefore beneficial effects of the association of a non-expansive porous material with Fe°-based filters to delay clogging by collecting corrosion products (CPs). 25%/50%/25% Fe°/S/PZ device allow to reduce greatly the proportion of iron in the reactive zone (RZ) since pure iron devices are not recommended due to clogging. 25% ≤ % Fe° ≤ 60%, 25% ≤ %S ≤ 50%, and 25% ≤ %Pz ≤ 50% could provide a necessary framework for all Fe°-bed filters.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Ranges and Fitting Ratios of Natural Aggregates for a Sustainable and Effective Fe°/Sand/Pozzolan Ternary Device Using Orange Methyl
    AU  - Suzanne Makota S. N.
    AU  - Nguemo Wekam Eleonore Armele
    AU  - Dipita Kolye Ernest Yves Herliche
    AU  - Nassi Achille
    Y1  - 2022/02/25
    PY  - 2022
    N1  - https://doi.org/10.11648/j.ajac.20221001.13
    DO  - 10.11648/j.ajac.20221001.13
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 15
    EP  - 27
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20221001.13
    AB  - The remediation effectiveness of a Fe°/Sand/Pozzolan (Fe°/S/Pz) ternary device using an azo-dye for characterization is demonstrated herein. Optimal operating conditions, which specify the proportions of solid materials, such as iron (Fe°), sand (S), and pozzolan (Pz), in the reactive zone (RZ), are essential factors for the performance of such heterogeneous devices. Thus, the operative indicator orange methyl (OM) of 2 mg/L was used. Performance parameters such as pH, released iron of the collected water, flow rate, and fading power were measured using filter devices containing (1) 100% Fe°, (2) 25%/75% Fe°/S, (3) 25%/75% Fe°/Pz, (4) 25%/0%/75% Fe°/S/Pz, (5) 25%/25%/50% Fe°/S/Pz and (6) 25%/50%/25% Fe°/S/Pz for a correlation of proportions, reactivity, and performance. The experiments lasted thirty (30) days per device. It turns out that ranges of 25% ≤ % Fe° ≤ 60%, 25% ≤ %S ≤ 50%, and 25% ≤ %Pz ≤ 50% are quite enough. The ternary device, in ratios of 25%/50%/25% Fe°/S/PZ, is an excellent decontaminant of orange methyl OM, with regulation of pH and residual iron levels, for acceptable flows. There are therefore beneficial effects of the association of a non-expansive porous material with Fe°-based filters to delay clogging by collecting corrosion products (CPs). 25%/50%/25% Fe°/S/PZ device allow to reduce greatly the proportion of iron in the reactive zone (RZ) since pure iron devices are not recommended due to clogging. 25% ≤ % Fe° ≤ 60%, 25% ≤ %S ≤ 50%, and 25% ≤ %Pz ≤ 50% could provide a necessary framework for all Fe°-bed filters.
    VL  - 10
    IS  - 1
    ER  - 

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Author Information
  • Department of Chemistry, Faculty of Sciences, University of Douala, Douala, Cameroon

  • Department of Chemistry, Faculty of Sciences, University of Douala, Douala, Cameroon

  • Department of Chemistry, Faculty of Sciences, University of Douala, Douala, Cameroon

  • Department of Chemistry, Faculty of Sciences, University of Douala, Douala, Cameroon

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