Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives

Tidiane Diop; Adrienne Ndiolene; Mouhamadou Abdoulaye Diallo; Daouda Ndoye

doi:doi:10.11648/j.ajac.20221002.11

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Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives

Tidiane Diop, Adrienne Ndiolene, Mouhamadou Abdoulaye Diallo, Daouda Ndoye

Published in American Journal of Applied Chemistry (Volume 10, Issue 2)

Received: 16 February 2022 Accepted: 7 March 2022 Published: 15 March 2022

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Abstract

Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu₂Sn]₄(μ₃-O)₂(μ₂-OH)₂(OSO₂R)₂ with R=4-HO-C₆H₄-(1) and CH₃-(2) have been synthetized and characterized by elemental analysis, FT-IR, ¹H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å³ and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn₄O₄ core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.

Published in	American Journal of Applied Chemistry (Volume 10, Issue 2)
DOI	10.11648/j.ajac.20221002.11
Page(s)	38-42
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Organostannoxane, Pyridine-3-sulfonate, 4-hydroxylbenzenesulfonate, Tetranuclear Ladder

References

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APA Style

Tidiane Diop, Adrienne Ndiolene, Mouhamadou Abdoulaye Diallo, Daouda Ndoye. (2022). Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. American Journal of Applied Chemistry, 10(2), 38-42. https://doi.org/10.11648/j.ajac.20221002.11

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ACS Style

Tidiane Diop; Adrienne Ndiolene; Mouhamadou Abdoulaye Diallo; Daouda Ndoye. Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. Am. J. Appl. Chem. 2022, 10(2), 38-42. doi: 10.11648/j.ajac.20221002.11

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AMA Style

Tidiane Diop, Adrienne Ndiolene, Mouhamadou Abdoulaye Diallo, Daouda Ndoye. Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. Am J Appl Chem. 2022;10(2):38-42. doi: 10.11648/j.ajac.20221002.11

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@article{10.11648/j.ajac.20221002.11,
  author = {Tidiane Diop and Adrienne Ndiolene and Mouhamadou Abdoulaye Diallo and Daouda Ndoye},
  title = {Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives},
  journal = {American Journal of Applied Chemistry},
  volume = {10},
  number = {2},
  pages = {38-42},
  doi = {10.11648/j.ajac.20221002.11},
  url = {https://doi.org/10.11648/j.ajac.20221002.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20221002.11},
  abstract = {Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu2Sn]4(μ3-O)2(μ2-OH)2(OSO2R)2 with R=4-HO-C6H4-(1) and CH3-(2) have been synthetized and characterized by elemental analysis, FT-IR, 1H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å3 and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn4O4 core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.},
 year = {2022}
}

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TY  - JOUR
T1  - Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives
AU  - Tidiane Diop
AU  - Adrienne Ndiolene
AU  - Mouhamadou Abdoulaye Diallo
AU  - Daouda Ndoye
Y1  - 2022/03/15
PY  - 2022
N1  - https://doi.org/10.11648/j.ajac.20221002.11
DO  - 10.11648/j.ajac.20221002.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 38
EP  - 42
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20221002.11
AB  - Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu2Sn]4(μ3-O)2(μ2-OH)2(OSO2R)2 with R=4-HO-C6H4-(1) and CH3-(2) have been synthetized and characterized by elemental analysis, FT-IR, 1H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å3 and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn4O4 core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.
VL  - 10
IS  - 2
ER  -

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Author Information

Tidiane Diop

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Adrienne Ndiolene

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Mouhamadou Abdoulaye Diallo

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Daouda Ndoye

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

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APA Style

Tidiane Diop, Adrienne Ndiolene, Mouhamadou Abdoulaye Diallo, Daouda Ndoye. (2022). Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. American Journal of Applied Chemistry, 10(2), 38-42. https://doi.org/10.11648/j.ajac.20221002.11

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ACS Style

Tidiane Diop; Adrienne Ndiolene; Mouhamadou Abdoulaye Diallo; Daouda Ndoye. Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. Am. J. Appl. Chem. 2022, 10(2), 38-42. doi: 10.11648/j.ajac.20221002.11

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AMA Style

Tidiane Diop, Adrienne Ndiolene, Mouhamadou Abdoulaye Diallo, Daouda Ndoye. Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. Am J Appl Chem. 2022;10(2):38-42. doi: 10.11648/j.ajac.20221002.11

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@article{10.11648/j.ajac.20221002.11,
  author = {Tidiane Diop and Adrienne Ndiolene and Mouhamadou Abdoulaye Diallo and Daouda Ndoye},
  title = {Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives},
  journal = {American Journal of Applied Chemistry},
  volume = {10},
  number = {2},
  pages = {38-42},
  doi = {10.11648/j.ajac.20221002.11},
  url = {https://doi.org/10.11648/j.ajac.20221002.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20221002.11},
  abstract = {Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu2Sn]4(μ3-O)2(μ2-OH)2(OSO2R)2 with R=4-HO-C6H4-(1) and CH3-(2) have been synthetized and characterized by elemental analysis, FT-IR, 1H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å3 and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn4O4 core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.},
 year = {2022}
}

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TY  - JOUR
T1  - Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives
AU  - Tidiane Diop
AU  - Adrienne Ndiolene
AU  - Mouhamadou Abdoulaye Diallo
AU  - Daouda Ndoye
Y1  - 2022/03/15
PY  - 2022
N1  - https://doi.org/10.11648/j.ajac.20221002.11
DO  - 10.11648/j.ajac.20221002.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 38
EP  - 42
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20221002.11
AB  - Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu2Sn]4(μ3-O)2(μ2-OH)2(OSO2R)2 with R=4-HO-C6H4-(1) and CH3-(2) have been synthetized and characterized by elemental analysis, FT-IR, 1H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å3 and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn4O4 core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.
VL  - 10
IS  - 2
ER  -

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