The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO<sub>3</sub>(M=Ce, La, Y) Catalysts

Ho Joon Seo

doi:doi:10.11648/j.ajche.20221001.11

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The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO₃(M=Ce, La, Y) Catalysts

Ho Joon Seo

Published in American Journal of Chemical Engineering (Volume 10, Issue 1)

Received: 3 December 2021 Accepted: 23 February 2022 Published: 4 March 2022

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Abstract

The catalytic yields of partial oxidation of methane (POM) to hydrogen over M(1)-Ni(5)/Al₂O₃(M=, Ce, La, Y) catalysts were investigated using a fixed bed flow reactor under atmospheric pressure to solve the global warming problem and clean energy demand. Catalyst activity is evaluated by performing the reaction of POM to hydrogen, and active sites of the catalyst are verified by instrumental analysis. The catalysts were characterized by XPS, XRD, FESEM, EDS, FETEM. The crystal phase behavior of reduced La(1)-Ni(5)/AlCeO₃ catalysts before and after the reaction were studied by XRD analysis. The crystalline phase of Ni and La on La(1)-Ni(5)/AlCeO₃ reduced before reaction was not obserbed due to uniform distribution of nanoparticles. FESEM and EDS analyses show that nanoparticles of Ni, La and Ce are uniformly distributed on the catalyst surface. In addition, TEM images and EDS mapping of La, Ni, Ce, O, and Al for a reduced La(1)-Ni(5)/AlCeO₃ catalyst before reaction show that the elements are well distributed. When 1 wt% of La was added to Ni(5)/AlCeO₃ catalyst, XPS results showed that O^-, O_vacancy, and O₂^- species, Ni₂p_3/2, and Ce3d_5/2increased 1.4, 52.7, 6.3% on the La(1)- Ni(5)/ AlCeO₃ catalyst, respectively. The yield of hydrogen on the La(1)- Ni(5)/ AlCeO₃ catalyst was 89.1%, which was much better than that of M(1)-Ni(5)/Al₂O₃(M=Ce, Y) catalysts. As Ce⁴⁺/Ce³⁺ ions in CeO₂ produced by the reaction of AlCeO₃ with oxygen were substitute to La³⁺, Ni²⁺, it made oxygen vacancies in the lattice and further improved the hydrogen yield by increasing the dispersion of Ni atoms with strong metal- support interaction (SMSI) effect.

Published in	American Journal of Chemical Engineering (Volume 10, Issue 1)
DOI	10.11648/j.ajche.20221001.11
Page(s)	1-10
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Hydrogen, Lanthanum, Partial Oxidation of Methane, Nickel, AlCeO₃

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Ho Joon Seo. (2022). The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts. American Journal of Chemical Engineering, 10(1), 1-10. https://doi.org/10.11648/j.ajche.20221001.11

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Ho Joon Seo. The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts. Am. J. Chem. Eng. 2022, 10(1), 1-10. doi: 10.11648/j.ajche.20221001.11

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Ho Joon Seo. The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts. Am J Chem Eng. 2022;10(1):1-10. doi: 10.11648/j.ajche.20221001.11

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@article{10.11648/j.ajche.20221001.11,
  author = {Ho Joon Seo},
  title = {The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts},
  journal = {American Journal of Chemical Engineering},
  volume = {10},
  number = {1},
  pages = {1-10},
  doi = {10.11648/j.ajche.20221001.11},
  url = {https://doi.org/10.11648/j.ajche.20221001.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20221001.11},
  abstract = {The catalytic yields of partial oxidation of methane (POM) to hydrogen over M(1)-Ni(5)/Al2O3(M=, Ce, La, Y) catalysts were investigated using a fixed bed flow reactor under atmospheric pressure to solve the global warming problem and clean energy demand. Catalyst activity is evaluated by performing the reaction of POM to hydrogen, and active sites of the catalyst are verified by instrumental analysis. The catalysts were characterized by XPS, XRD, FESEM, EDS, FETEM. The crystal phase behavior of reduced La(1)-Ni(5)/AlCeO3 catalysts before and after the reaction were studied by XRD analysis. The crystalline phase of Ni and La on La(1)-Ni(5)/AlCeO3 reduced before reaction was not obserbed due to uniform distribution of nanoparticles. FESEM and EDS analyses show that nanoparticles of Ni, La and Ce are uniformly distributed on the catalyst surface. In addition, TEM images and EDS mapping of La, Ni, Ce, O, and Al for a reduced La(1)-Ni(5)/AlCeO3 catalyst before reaction show that the elements are well distributed. When 1 wt% of La was added to Ni(5)/AlCeO3 catalyst, XPS results showed that O-, Ovacancy, and O2- species, Ni2p3/2, and Ce3d5/2 increased 1.4, 52.7, 6.3% on the La(1)- Ni(5)/ AlCeO3 catalyst, respectively. The yield of hydrogen on the La(1)- Ni(5)/ AlCeO3 catalyst was 89.1%, which was much better than that of M(1)-Ni(5)/Al2O3(M=Ce, Y) catalysts. As Ce4+/Ce3+ ions in CeO2 produced by the reaction of AlCeO3 with oxygen were substitute to La3+, Ni2+, it made oxygen vacancies in the lattice and further improved the hydrogen yield by increasing the dispersion of Ni atoms with strong metal- support interaction (SMSI) effect.},
 year = {2022}
}

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TY  - JOUR
T1  - The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts
AU  - Ho Joon Seo
Y1  - 2022/03/04
PY  - 2022
N1  - https://doi.org/10.11648/j.ajche.20221001.11
DO  - 10.11648/j.ajche.20221001.11
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 1
EP  - 10
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20221001.11
AB  - The catalytic yields of partial oxidation of methane (POM) to hydrogen over M(1)-Ni(5)/Al2O3(M=, Ce, La, Y) catalysts were investigated using a fixed bed flow reactor under atmospheric pressure to solve the global warming problem and clean energy demand. Catalyst activity is evaluated by performing the reaction of POM to hydrogen, and active sites of the catalyst are verified by instrumental analysis. The catalysts were characterized by XPS, XRD, FESEM, EDS, FETEM. The crystal phase behavior of reduced La(1)-Ni(5)/AlCeO3 catalysts before and after the reaction were studied by XRD analysis. The crystalline phase of Ni and La on La(1)-Ni(5)/AlCeO3 reduced before reaction was not obserbed due to uniform distribution of nanoparticles. FESEM and EDS analyses show that nanoparticles of Ni, La and Ce are uniformly distributed on the catalyst surface. In addition, TEM images and EDS mapping of La, Ni, Ce, O, and Al for a reduced La(1)-Ni(5)/AlCeO3 catalyst before reaction show that the elements are well distributed. When 1 wt% of La was added to Ni(5)/AlCeO3 catalyst, XPS results showed that O-, Ovacancy, and O2- species, Ni2p3/2, and Ce3d5/2 increased 1.4, 52.7, 6.3% on the La(1)- Ni(5)/ AlCeO3 catalyst, respectively. The yield of hydrogen on the La(1)- Ni(5)/ AlCeO3 catalyst was 89.1%, which was much better than that of M(1)-Ni(5)/Al2O3(M=Ce, Y) catalysts. As Ce4+/Ce3+ ions in CeO2 produced by the reaction of AlCeO3 with oxygen were substitute to La3+, Ni2+, it made oxygen vacancies in the lattice and further improved the hydrogen yield by increasing the dispersion of Ni atoms with strong metal- support interaction (SMSI) effect.
VL  - 10
IS  - 1
ER  -

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Ho Joon Seo

Department of Chemical and Biomolecular Engineering, Chonnam National University, Yosu, Republic of Korea

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Ho Joon Seo. (2022). The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts. American Journal of Chemical Engineering, 10(1), 1-10. https://doi.org/10.11648/j.ajche.20221001.11

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Ho Joon Seo. The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts. Am. J. Chem. Eng. 2022, 10(1), 1-10. doi: 10.11648/j.ajche.20221001.11

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AMA Style

Ho Joon Seo. The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts. Am J Chem Eng. 2022;10(1):1-10. doi: 10.11648/j.ajche.20221001.11

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@article{10.11648/j.ajche.20221001.11,
  author = {Ho Joon Seo},
  title = {The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts},
  journal = {American Journal of Chemical Engineering},
  volume = {10},
  number = {1},
  pages = {1-10},
  doi = {10.11648/j.ajche.20221001.11},
  url = {https://doi.org/10.11648/j.ajche.20221001.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20221001.11},
  abstract = {The catalytic yields of partial oxidation of methane (POM) to hydrogen over M(1)-Ni(5)/Al2O3(M=, Ce, La, Y) catalysts were investigated using a fixed bed flow reactor under atmospheric pressure to solve the global warming problem and clean energy demand. Catalyst activity is evaluated by performing the reaction of POM to hydrogen, and active sites of the catalyst are verified by instrumental analysis. The catalysts were characterized by XPS, XRD, FESEM, EDS, FETEM. The crystal phase behavior of reduced La(1)-Ni(5)/AlCeO3 catalysts before and after the reaction were studied by XRD analysis. The crystalline phase of Ni and La on La(1)-Ni(5)/AlCeO3 reduced before reaction was not obserbed due to uniform distribution of nanoparticles. FESEM and EDS analyses show that nanoparticles of Ni, La and Ce are uniformly distributed on the catalyst surface. In addition, TEM images and EDS mapping of La, Ni, Ce, O, and Al for a reduced La(1)-Ni(5)/AlCeO3 catalyst before reaction show that the elements are well distributed. When 1 wt% of La was added to Ni(5)/AlCeO3 catalyst, XPS results showed that O-, Ovacancy, and O2- species, Ni2p3/2, and Ce3d5/2 increased 1.4, 52.7, 6.3% on the La(1)- Ni(5)/ AlCeO3 catalyst, respectively. The yield of hydrogen on the La(1)- Ni(5)/ AlCeO3 catalyst was 89.1%, which was much better than that of M(1)-Ni(5)/Al2O3(M=Ce, Y) catalysts. As Ce4+/Ce3+ ions in CeO2 produced by the reaction of AlCeO3 with oxygen were substitute to La3+, Ni2+, it made oxygen vacancies in the lattice and further improved the hydrogen yield by increasing the dispersion of Ni atoms with strong metal- support interaction (SMSI) effect.},
 year = {2022}
}

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TY  - JOUR
T1  - The Partial Oxidation of Methane to Hydrogen over M(1)-Ni(5)/AlCeO3(M=Ce, La, Y) Catalysts
AU  - Ho Joon Seo
Y1  - 2022/03/04
PY  - 2022
N1  - https://doi.org/10.11648/j.ajche.20221001.11
DO  - 10.11648/j.ajche.20221001.11
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 1
EP  - 10
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20221001.11
AB  - The catalytic yields of partial oxidation of methane (POM) to hydrogen over M(1)-Ni(5)/Al2O3(M=, Ce, La, Y) catalysts were investigated using a fixed bed flow reactor under atmospheric pressure to solve the global warming problem and clean energy demand. Catalyst activity is evaluated by performing the reaction of POM to hydrogen, and active sites of the catalyst are verified by instrumental analysis. The catalysts were characterized by XPS, XRD, FESEM, EDS, FETEM. The crystal phase behavior of reduced La(1)-Ni(5)/AlCeO3 catalysts before and after the reaction were studied by XRD analysis. The crystalline phase of Ni and La on La(1)-Ni(5)/AlCeO3 reduced before reaction was not obserbed due to uniform distribution of nanoparticles. FESEM and EDS analyses show that nanoparticles of Ni, La and Ce are uniformly distributed on the catalyst surface. In addition, TEM images and EDS mapping of La, Ni, Ce, O, and Al for a reduced La(1)-Ni(5)/AlCeO3 catalyst before reaction show that the elements are well distributed. When 1 wt% of La was added to Ni(5)/AlCeO3 catalyst, XPS results showed that O-, Ovacancy, and O2- species, Ni2p3/2, and Ce3d5/2 increased 1.4, 52.7, 6.3% on the La(1)- Ni(5)/ AlCeO3 catalyst, respectively. The yield of hydrogen on the La(1)- Ni(5)/ AlCeO3 catalyst was 89.1%, which was much better than that of M(1)-Ni(5)/Al2O3(M=Ce, Y) catalysts. As Ce4+/Ce3+ ions in CeO2 produced by the reaction of AlCeO3 with oxygen were substitute to La3+, Ni2+, it made oxygen vacancies in the lattice and further improved the hydrogen yield by increasing the dispersion of Ni atoms with strong metal- support interaction (SMSI) effect.
VL  - 10
IS  - 1
ER  -

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