Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater

Md. Sohel Rana; Nazia Rahman; Tofail Ahmed Chowdhury; Nirmal Chandra Dafader; Shahnaz Sultana; Md. Nabul Sardar; Md. Nahid Kayser

doi:doi:10.11648/j.ajpst.20210701.11

Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater

Md. Sohel Rana, Nazia Rahman, Tofail Ahmed Chowdhury, Nirmal Chandra Dafader, Shahnaz Sultana, Md. Nabul Sardar, Md. Nahid Kayser

Published in American Journal of Polymer Science and Technology (Volume 7, Issue 1)

Received: 26 November 2020 Accepted: 28 December 2020 Published: 15 January 2021

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Abstract

An environmental affable, economically feasible and reusable sulfonated adsorbent were constructed by gamma radiation grafting of glycidyl methacrylate (GMA) on non-woven polyethylene fabric and subsequent chemical modification. Highest graft yield of 343.31% was obtained at favourable conditions: 30 kGy radiation dose, 5% monomer concentration, adding up of 0.5% Tween-20 as an additive, 4 h reaction time. The epoxide group containing GMA-g-PE film were functionalized through sulfonation. The adsorbent was identified by Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Thermo-gravimetric Analysis (TGA). The aqueous solutions of methylene blue were prepared in various concentrations and adsorption behavior by the developed sulfonated-GMA-g-PE film were investigated. MB uptake capacity at different environment such as contact time, pH and initial MB concentration were identified. The adsorption of MB is highly pH dependent and utmost sorption was found at pH 7. The kinetic adsorption data were interpreted by pseudo-ﬁrst-order and pseudo-second-order equations. Pseudo-ﬁrst-order rate kinetic model is more applicable for the sorption process due to its higher correlation coefficient. From the two isotherm model Langmuir and Fruendlich, Fruendlich model attuned best with the MB sorption as presented by higher correlation coefficient. The MB uptake capacity of the sorbent obtained from Langmuir model was 500 mg/g. Futhermore, the adsorbent could be reformed and reused repeatedly for the sorption of MB from waste water.

Published in	American Journal of Polymer Science and Technology (Volume 7, Issue 1)
DOI	10.11648/j.ajpst.20210701.11
Page(s)	1-9
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Radiation, GMA, Methylene Blue, Isotherm, Kinetics

References

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Md. Sohel Rana, Nazia Rahman, Tofail Ahmed Chowdhury, Nirmal Chandra Dafader, Shahnaz Sultana, et al. (2021). Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater. American Journal of Polymer Science and Technology, 7(1), 1-9. https://doi.org/10.11648/j.ajpst.20210701.11

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ACS Style

Md. Sohel Rana; Nazia Rahman; Tofail Ahmed Chowdhury; Nirmal Chandra Dafader; Shahnaz Sultana, et al. Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater. Am. J. Polym. Sci. Technol. 2021, 7(1), 1-9. doi: 10.11648/j.ajpst.20210701.11

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AMA Style

Md. Sohel Rana, Nazia Rahman, Tofail Ahmed Chowdhury, Nirmal Chandra Dafader, Shahnaz Sultana, et al. Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater. Am J Polym Sci Technol. 2021;7(1):1-9. doi: 10.11648/j.ajpst.20210701.11

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@article{10.11648/j.ajpst.20210701.11,
  author = {Md. Sohel Rana and Nazia Rahman and Tofail Ahmed Chowdhury and Nirmal Chandra Dafader and Shahnaz Sultana and Md. Nabul Sardar and Md. Nahid Kayser},
  title = {Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater},
  journal = {American Journal of Polymer Science and Technology},
  volume = {7},
  number = {1},
  pages = {1-9},
  doi = {10.11648/j.ajpst.20210701.11},
  url = {https://doi.org/10.11648/j.ajpst.20210701.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20210701.11},
  abstract = {An environmental affable, economically feasible and reusable sulfonated adsorbent were constructed by gamma radiation grafting of glycidyl methacrylate (GMA) on non-woven polyethylene fabric and subsequent chemical modification. Highest graft yield of 343.31% was obtained at favourable conditions: 30 kGy radiation dose, 5% monomer concentration, adding up of 0.5% Tween-20 as an additive, 4 h reaction time. The epoxide group containing GMA-g-PE film were functionalized through sulfonation. The adsorbent was identified by Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Thermo-gravimetric Analysis (TGA). The aqueous solutions of methylene blue were prepared in various concentrations and adsorption behavior by the developed sulfonated-GMA-g-PE film were investigated. MB uptake capacity at different environment such as contact time, pH and initial MB concentration were identified. The adsorption of MB is highly pH dependent and utmost sorption was found at pH 7. The kinetic adsorption data were interpreted by pseudo-ﬁrst-order and pseudo-second-order equations. Pseudo-ﬁrst-order rate kinetic model is more applicable for the sorption process due to its higher correlation coefficient. From the two isotherm model Langmuir and Fruendlich, Fruendlich model attuned best with the MB sorption as presented by higher correlation coefficient. The MB uptake capacity of the sorbent obtained from Langmuir model was 500 mg/g. Futhermore, the adsorbent could be reformed and reused repeatedly for the sorption of MB from waste water.},
 year = {2021}
}

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TY - JOUR
T1 - Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater
AU - Md. Sohel Rana
AU - Nazia Rahman
AU - Tofail Ahmed Chowdhury
AU - Nirmal Chandra Dafader
AU - Shahnaz Sultana
AU - Md. Nabul Sardar
AU - Md. Nahid Kayser
Y1 - 2021/01/15
PY - 2021
N1 - https://doi.org/10.11648/j.ajpst.20210701.11
DO - 10.11648/j.ajpst.20210701.11
T2 - American Journal of Polymer Science and Technology
JF - American Journal of Polymer Science and Technology
JO - American Journal of Polymer Science and Technology
SP - 1
EP - 9
PB - Science Publishing Group
SN - 2575-5986
UR - https://doi.org/10.11648/j.ajpst.20210701.11
AB - An environmental affable, economically feasible and reusable sulfonated adsorbent were constructed by gamma radiation grafting of glycidyl methacrylate (GMA) on non-woven polyethylene fabric and subsequent chemical modification. Highest graft yield of 343.31% was obtained at favourable conditions: 30 kGy radiation dose, 5% monomer concentration, adding up of 0.5% Tween-20 as an additive, 4 h reaction time. The epoxide group containing GMA-g-PE film were functionalized through sulfonation. The adsorbent was identified by Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Thermo-gravimetric Analysis (TGA). The aqueous solutions of methylene blue were prepared in various concentrations and adsorption behavior by the developed sulfonated-GMA-g-PE film were investigated. MB uptake capacity at different environment such as contact time, pH and initial MB concentration were identified. The adsorption of MB is highly pH dependent and utmost sorption was found at pH 7. The kinetic adsorption data were interpreted by pseudo-ﬁrst-order and pseudo-second-order equations. Pseudo-ﬁrst-order rate kinetic model is more applicable for the sorption process due to its higher correlation coefficient. From the two isotherm model Langmuir and Fruendlich, Fruendlich model attuned best with the MB sorption as presented by higher correlation coefficient. The MB uptake capacity of the sorbent obtained from Langmuir model was 500 mg/g. Futhermore, the adsorbent could be reformed and reused repeatedly for the sorption of MB from waste water.
VL - 7
IS - 1
ER -

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Author Information

Md. Sohel Rana

Nuclear and Radiation Chemistry Division, Institute of Nuclear Science and Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, Bangladesh
Nazia Rahman

Nuclear and Radiation Chemistry Division, Institute of Nuclear Science and Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, Bangladesh
Tofail Ahmed Chowdhury

Department of Chemistry, University of Dhaka, Dhaka, Bangladesh
Nirmal Chandra Dafader

Nuclear and Radiation Chemistry Division, Institute of Nuclear Science and Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, Bangladesh
Shahnaz Sultana

Nuclear and Radiation Chemistry Division, Institute of Nuclear Science and Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, Bangladesh
Md. Nabul Sardar

Nuclear and Radiation Chemistry Division, Institute of Nuclear Science and Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, Bangladesh
Md. Nahid Kayser

Nuclear and Radiation Chemistry Division, Institute of Nuclear Science and Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, Bangladesh

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APA Style

Md. Sohel Rana, Nazia Rahman, Tofail Ahmed Chowdhury, Nirmal Chandra Dafader, Shahnaz Sultana, et al. (2021). Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater. American Journal of Polymer Science and Technology, 7(1), 1-9. https://doi.org/10.11648/j.ajpst.20210701.11

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ACS Style

Md. Sohel Rana; Nazia Rahman; Tofail Ahmed Chowdhury; Nirmal Chandra Dafader; Shahnaz Sultana, et al. Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater. Am. J. Polym. Sci. Technol. 2021, 7(1), 1-9. doi: 10.11648/j.ajpst.20210701.11

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AMA Style

Md. Sohel Rana, Nazia Rahman, Tofail Ahmed Chowdhury, Nirmal Chandra Dafader, Shahnaz Sultana, et al. Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater. Am J Polym Sci Technol. 2021;7(1):1-9. doi: 10.11648/j.ajpst.20210701.11

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@article{10.11648/j.ajpst.20210701.11,
  author = {Md. Sohel Rana and Nazia Rahman and Tofail Ahmed Chowdhury and Nirmal Chandra Dafader and Shahnaz Sultana and Md. Nabul Sardar and Md. Nahid Kayser},
  title = {Application of Sulfonated GMA-g-non Woven PE Fabric for the Efficient Removal of Methylene Blue Dye from Wastewater},
  journal = {American Journal of Polymer Science and Technology},
  volume = {7},
  number = {1},
  pages = {1-9},
  doi = {10.11648/j.ajpst.20210701.11},
  url = {https://doi.org/10.11648/j.ajpst.20210701.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20210701.11},
  abstract = {An environmental affable, economically feasible and reusable sulfonated adsorbent were constructed by gamma radiation grafting of glycidyl methacrylate (GMA) on non-woven polyethylene fabric and subsequent chemical modification. Highest graft yield of 343.31% was obtained at favourable conditions: 30 kGy radiation dose, 5% monomer concentration, adding up of 0.5% Tween-20 as an additive, 4 h reaction time. The epoxide group containing GMA-g-PE film were functionalized through sulfonation. The adsorbent was identified by Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Thermo-gravimetric Analysis (TGA). The aqueous solutions of methylene blue were prepared in various concentrations and adsorption behavior by the developed sulfonated-GMA-g-PE film were investigated. MB uptake capacity at different environment such as contact time, pH and initial MB concentration were identified. The adsorption of MB is highly pH dependent and utmost sorption was found at pH 7. The kinetic adsorption data were interpreted by pseudo-ﬁrst-order and pseudo-second-order equations. Pseudo-ﬁrst-order rate kinetic model is more applicable for the sorption process due to its higher correlation coefficient. From the two isotherm model Langmuir and Fruendlich, Fruendlich model attuned best with the MB sorption as presented by higher correlation coefficient. The MB uptake capacity of the sorbent obtained from Langmuir model was 500 mg/g. Futhermore, the adsorbent could be reformed and reused repeatedly for the sorption of MB from waste water.},
 year = {2021}
}

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