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Effect of Secondary Graphitization Expansion on Micro-shrinkage Porosity of Ductile Iron

Received: 28 June 2022    Accepted: 18 July 2022    Published: 9 August 2022
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Abstract

Secondary graphitization annealing is often used to obtain 100% ferrite matrix in the production of ductile iron. The volume expansion of pearlite will occur during secondary graphitization annealing. So far, whether this expansion can affect the micro-shrinkage porosity between the austenite rings surrounding the graphite nodule during solidification has not attracted people's attention, while micro-shrinkage porosity is one of the primary factors affecting the impact toughness of ductile iron at ultra-low temperature. Aiming at the problem of whether the secondary graphitization of ductile iron affects the micro-shrinkage porosity, the secondary graphitization annealing of pearlitic ductile iron is carried out, and the effect of secondary graphitization expansion on micro-shrinkage porosity was studied. The metallographic microstructures and micro-shrinkage porosity are observed by Axiovert200MAT metallographic microscope and MLA250 (FEIQuanta) scanning electron microscope. The maximum length of micro-shrinkage porosity is measured by Nano Measurer 1.2 and the maximum area is measured by Photoshop software. The results show that the volume expansion rates of ductile iron and gray cast iron after secondary graphitization annealing are about 1.2% and 1.4%, respectively. After secondary graphitization annealing, the size and quantity of micro-shrinkage porosity of ductile iron decrease. It indicates that the expansion after secondary graphitization of cast iron will help to repaire micro-shrinkage porosity.

Published in Advances in Materials (Volume 11, Issue 3)
DOI 10.11648/j.am.20221103.13
Page(s) 69-76
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Ductile Iron, Gray Cast Iron, Secondary Graphitization, Expansion Rate, Micro-shrinkage Porosity

References
[1] Toktas G, Toktas A, Tayanc M. Influence of matrix structure on the fatigue properties of an alloyed ductile iron. Materials and Design, 2008, 29 (8): 1600-1608.
[2] Zhang K, Liu J D, Song X F, et al. Investigation on low-temperature impact toughness of heavy-section nodular iron. Modern Cast Iron, 2017, 37 (3): 41-45.
[3] David P, Massone J, Boeri R, et al. Mechanical properties of thin wall ductile iron-influence of carbon equivalent and graphite distribution. ISIJ International, 2004, 44 (7): 1180-1187.
[4] Caldera M, Massone J M, Boeri R E, et al. Impact properties of thin wall ductile iron. ISIJ International, 2004, 44 (4): 731-736.
[5] Torsten S G, Ingvar L S. The effect of graphite fraction and morphologyon the plastic deformation behavior of cast irons. Metallurgical andMaterialsTransactionsA, 2007, 38 (4): 840-847.
[6] Iacoviello F, Cocco V D. Influence of the graphite elements morphology on the fatigue crack propagation mechanisms in a ferritic ductile cast iron. Engineering Fracture Mechanics, 2016, 167 (11): 248-258.
[7] Costa Nuno, Machado Nuno, Silva Filipe Samuel. Influence of graphite nodules geometrical featureson fatigue life ofhigh-strength nodularcastiron. JMEPEG, 2008, 17 (3): 352-362.
[8] Chen D, Sang w w, Wu L X, et al. Study on Thermal Fatigue Crack Initiation and Propagation Behavior in Nodular Cast Iron. Foundry Technology, 2018, 39 (2): 482-432.
[9] Diao X G, Ning Z L, Cao F Y, et al. Graphite morphology evolution during melt holding of ductile iron. Key Engineering Materials, 2011, 457: 31-36.
[10] Herbert Werner. Mischkristallverfestigte EN-GJS-Werkstoff fuer Gross-und Schwergussteile. Giesserei, 2016, 103 (2): 38-42.
[11] Jacaze J, Larranaga P, Asenjo I, et al. Sertucha Influence of 1wt% addijion of Ni on structural and mechanical properties of ferritic ductile irons. Materials Science and Technology, 2012, 28 (5): 603-608.
[12] Sun Y F, Hu S M, Xiao Z Y, et al. Effects of nickel on low-temperature impact toughness and corrosion resistance of high-ductile iron. Materials and Design, 2012, 41: 37-42.
[13] Zhang X N, Qu Y D, Yang H W, et al. Temperature impact toughness and fracture mechanism of cast QT400-18L ductile iron with different Ni additions. China Foundry, 2013, 10 (5): 310-314.
[14] Chen X G, Xu J, Hu H, et al. Effects of niobium addition on microstructure and tensile behavior of as-cast ductile iron. Materials Science and Engineering A, 2017, 688 (3): 416-428.
[15] Verdu C, Adrien J, Buffière J Y. Three-dimensional shape of the early stages of fatigue cracks nucleated in nodular cast iron. Materials science and engineering A, 2008, 483-484: 402-405.
[16] Verdu C, Adrien J, Reynaud A. Contributions of dual phase heat treatments to fatigue properties of SG cast irons. International Journal of Cast Metal Research, 2005, 18 (6): 346-354.
[17] Guo E J. Effect of Ce-Mg-Si and Y-Mg-Si nodulizers on the microstructures and mechanical properties of heavy section ductile iron. Journal of rare earths, 2014. 32 (8): 38-744.
[18] Gao M Q, Li G L, You J H. Cementites decomposition of a pearlitic ductile cast iron during graphitization annealing heat treatment. Journal of iron and steel research international. 2017. 24: 838-843.
[19] Hou Chao, Rrn Wei, Song Jia-jian, et al. Effects of Microshrinkage on Low Temperature Toughness of Ferritic Ductile Iron. Fundry, 2019, 68 (2): 123-127.
[20] Cai Hong, Lu Jun, Wang Zhi-ming, et al. Structure of Cementite and Morphology of Primary Cementite. Heat Treatment, 2010, 25 (2): 50-53.
[21] Lou Guobiao, Tao Yuchao, Chen Wulong, et al. Experimental Investigation of Mechanical Properties of TSZ410 Ferritic Stainless Steel at Elevated Temperature. JOURNAL OF TONGJI UNIVERSITY (NATURAL SCIENCE), 2021, 49 (1): 20-29.
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    Shuying Chen, Qingchun Li, Jiajian Song, Ming Sun, Haiqing Sun, et al. (2022). Effect of Secondary Graphitization Expansion on Micro-shrinkage Porosity of Ductile Iron. Advances in Materials, 11(3), 69-76. https://doi.org/10.11648/j.am.20221103.13

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    ACS Style

    Shuying Chen; Qingchun Li; Jiajian Song; Ming Sun; Haiqing Sun, et al. Effect of Secondary Graphitization Expansion on Micro-shrinkage Porosity of Ductile Iron. Adv. Mater. 2022, 11(3), 69-76. doi: 10.11648/j.am.20221103.13

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    AMA Style

    Shuying Chen, Qingchun Li, Jiajian Song, Ming Sun, Haiqing Sun, et al. Effect of Secondary Graphitization Expansion on Micro-shrinkage Porosity of Ductile Iron. Adv Mater. 2022;11(3):69-76. doi: 10.11648/j.am.20221103.13

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  • @article{10.11648/j.am.20221103.13,
      author = {Shuying Chen and Qingchun Li and Jiajian Song and Ming Sun and Haiqing Sun and Guowei Chang},
      title = {Effect of Secondary Graphitization Expansion on Micro-shrinkage Porosity of Ductile Iron},
      journal = {Advances in Materials},
      volume = {11},
      number = {3},
      pages = {69-76},
      doi = {10.11648/j.am.20221103.13},
      url = {https://doi.org/10.11648/j.am.20221103.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20221103.13},
      abstract = {Secondary graphitization annealing is often used to obtain 100% ferrite matrix in the production of ductile iron. The volume expansion of pearlite will occur during secondary graphitization annealing. So far, whether this expansion can affect the micro-shrinkage porosity between the austenite rings surrounding the graphite nodule during solidification has not attracted people's attention, while micro-shrinkage porosity is one of the primary factors affecting the impact toughness of ductile iron at ultra-low temperature. Aiming at the problem of whether the secondary graphitization of ductile iron affects the micro-shrinkage porosity, the secondary graphitization annealing of pearlitic ductile iron is carried out, and the effect of secondary graphitization expansion on micro-shrinkage porosity was studied. The metallographic microstructures and micro-shrinkage porosity are observed by Axiovert200MAT metallographic microscope and MLA250 (FEIQuanta) scanning electron microscope. The maximum length of micro-shrinkage porosity is measured by Nano Measurer 1.2 and the maximum area is measured by Photoshop software. The results show that the volume expansion rates of ductile iron and gray cast iron after secondary graphitization annealing are about 1.2% and 1.4%, respectively. After secondary graphitization annealing, the size and quantity of micro-shrinkage porosity of ductile iron decrease. It indicates that the expansion after secondary graphitization of cast iron will help to repaire micro-shrinkage porosity.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Effect of Secondary Graphitization Expansion on Micro-shrinkage Porosity of Ductile Iron
    AU  - Shuying Chen
    AU  - Qingchun Li
    AU  - Jiajian Song
    AU  - Ming Sun
    AU  - Haiqing Sun
    AU  - Guowei Chang
    Y1  - 2022/08/09
    PY  - 2022
    N1  - https://doi.org/10.11648/j.am.20221103.13
    DO  - 10.11648/j.am.20221103.13
    T2  - Advances in Materials
    JF  - Advances in Materials
    JO  - Advances in Materials
    SP  - 69
    EP  - 76
    PB  - Science Publishing Group
    SN  - 2327-252X
    UR  - https://doi.org/10.11648/j.am.20221103.13
    AB  - Secondary graphitization annealing is often used to obtain 100% ferrite matrix in the production of ductile iron. The volume expansion of pearlite will occur during secondary graphitization annealing. So far, whether this expansion can affect the micro-shrinkage porosity between the austenite rings surrounding the graphite nodule during solidification has not attracted people's attention, while micro-shrinkage porosity is one of the primary factors affecting the impact toughness of ductile iron at ultra-low temperature. Aiming at the problem of whether the secondary graphitization of ductile iron affects the micro-shrinkage porosity, the secondary graphitization annealing of pearlitic ductile iron is carried out, and the effect of secondary graphitization expansion on micro-shrinkage porosity was studied. The metallographic microstructures and micro-shrinkage porosity are observed by Axiovert200MAT metallographic microscope and MLA250 (FEIQuanta) scanning electron microscope. The maximum length of micro-shrinkage porosity is measured by Nano Measurer 1.2 and the maximum area is measured by Photoshop software. The results show that the volume expansion rates of ductile iron and gray cast iron after secondary graphitization annealing are about 1.2% and 1.4%, respectively. After secondary graphitization annealing, the size and quantity of micro-shrinkage porosity of ductile iron decrease. It indicates that the expansion after secondary graphitization of cast iron will help to repaire micro-shrinkage porosity.
    VL  - 11
    IS  - 3
    ER  - 

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Author Information
  • School of Materials Science and Engineering, Liaoning University of Technology, Jinzhou, China

  • School of Materials Science and Engineering, Liaoning University of Technology, Jinzhou, China

  • Jinzhou Jietong Railway Machinery Manufacturing Co., Ltd, Jinzhou, China

  • Jinzhou Jietong Railway Machinery Manufacturing Co., Ltd, Jinzhou, China

  • Jinzhou Jietong Railway Machinery Manufacturing Co., Ltd, Jinzhou, China

  • School of Materials Science and Engineering, Liaoning University of Technology, Jinzhou, China

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