Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]

Mouhamadou Birame Diop; Modou Sarr; Mouhamadou Sembene Boye; Sérigne Cissé; Libasse Diop; Allen G. Oliver; David Renald

doi:doi:10.11648/j.am.20221104.12

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Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C₃₈H₃₀N₈)₂•CoCl₄] and [(CH₃NH₃)₂•CoCl₄]

Mouhamadou Birame Diop, Modou Sarr, Mouhamadou Sembene Boye, Sérigne Cissé, Libasse Diop, Allen G. Oliver, David Renald

Published in Advances in Materials (Volume 11, Issue 4)

Received: 7 October 2022 Accepted: 24 October 2022 Published: 30 October 2022

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Abstract

Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C₃₈H₃₀N₈)₂•CoCl₄] (1), crystallizes in the monoclinic space group P2₁/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å³. Compound [(CH₃NH₃)₂•CoCl₄] (2), crystallizes in the monoclinic space group P2₁/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å³. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R²₂(4), R³₄(10), R⁴₄(12), R⁵₅(14), R⁴₆(14), R⁵₆(16) and R⁶₆(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R²₁(4) rings and other hydrogen bonds of D type.

Published in	Advances in Materials (Volume 11, Issue 4)
DOI	10.11648/j.am.20221104.12
Page(s)	85-93
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

2,3,5-Triphenyltetrazolium, Methylammonium, Cobalt (II), Single Crystal X-ray Crystallography, 3D Structure

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Mouhamadou Birame Diop, Modou Sarr, Mouhamadou Sembene Boye, Sérigne Cissé, Libasse Diop, et al. (2022). Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Advances in Materials, 11(4), 85-93. https://doi.org/10.11648/j.am.20221104.12

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Mouhamadou Birame Diop; Modou Sarr; Mouhamadou Sembene Boye; Sérigne Cissé; Libasse Diop, et al. Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Adv. Mater. 2022, 11(4), 85-93. doi: 10.11648/j.am.20221104.12

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Mouhamadou Birame Diop, Modou Sarr, Mouhamadou Sembene Boye, Sérigne Cissé, Libasse Diop, et al. Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Adv Mater. 2022;11(4):85-93. doi: 10.11648/j.am.20221104.12

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@article{10.11648/j.am.20221104.12,
  author = {Mouhamadou Birame Diop and Modou Sarr and Mouhamadou Sembene Boye and Sérigne Cissé and Libasse Diop and Allen G. Oliver and David Renald},
  title = {Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]},
  journal = {Advances in Materials},
  volume = {11},
  number = {4},
  pages = {85-93},
  doi = {10.11648/j.am.20221104.12},
  url = {https://doi.org/10.11648/j.am.20221104.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20221104.12},
  abstract = {Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C38H30N8)2•CoCl4] (1), crystallizes in the monoclinic space group P21/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å3. Compound [(CH3NH3)2•CoCl4] (2), crystallizes in the monoclinic space group P21/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å3. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R22(4), R34(10), R44(12), R55(14), R46(14), R56(16) and R66(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R21(4) rings and other hydrogen bonds of D type.},
 year = {2022}
}

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TY  - JOUR
T1  - Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]
AU  - Mouhamadou Birame Diop
AU  - Modou Sarr
AU  - Mouhamadou Sembene Boye
AU  - Sérigne Cissé
AU  - Libasse Diop
AU  - Allen G. Oliver
AU  - David Renald
Y1  - 2022/10/30
PY  - 2022
N1  - https://doi.org/10.11648/j.am.20221104.12
DO  - 10.11648/j.am.20221104.12
T2  - Advances in Materials
JF  - Advances in Materials
JO  - Advances in Materials
SP  - 85
EP  - 93
PB  - Science Publishing Group
SN  - 2327-252X
UR  - https://doi.org/10.11648/j.am.20221104.12
AB  - Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C38H30N8)2•CoCl4] (1), crystallizes in the monoclinic space group P21/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å3. Compound [(CH3NH3)2•CoCl4] (2), crystallizes in the monoclinic space group P21/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å3. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R22(4), R34(10), R44(12), R55(14), R46(14), R56(16) and R66(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R21(4) rings and other hydrogen bonds of D type.
VL  - 11
IS  - 4
ER  -

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Author Information

Mouhamadou Birame Diop

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Modou Sarr

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Mouhamadou Sembene Boye

Department of Physic and Chemistry, Faculty of Science and Technology of Education and Training, Cheikh Anta Diop University, Dakar, Senegal
Sérigne Cissé

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Libasse Diop

Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Allen G. Oliver

Department of Chemistry and Biochemistry, University of Notre Dame, Nieuwland, USA
David Renald

Reactivity and Solid State Chemistry Laboratory, University of Picardie, Jules Verne, Amiens, France

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Mouhamadou Birame Diop, Modou Sarr, Mouhamadou Sembene Boye, Sérigne Cissé, Libasse Diop, et al. (2022). Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Advances in Materials, 11(4), 85-93. https://doi.org/10.11648/j.am.20221104.12

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Mouhamadou Birame Diop; Modou Sarr; Mouhamadou Sembene Boye; Sérigne Cissé; Libasse Diop, et al. Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Adv. Mater. 2022, 11(4), 85-93. doi: 10.11648/j.am.20221104.12

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Mouhamadou Birame Diop, Modou Sarr, Mouhamadou Sembene Boye, Sérigne Cissé, Libasse Diop, et al. Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]. Adv Mater. 2022;11(4):85-93. doi: 10.11648/j.am.20221104.12

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@article{10.11648/j.am.20221104.12,
  author = {Mouhamadou Birame Diop and Modou Sarr and Mouhamadou Sembene Boye and Sérigne Cissé and Libasse Diop and Allen G. Oliver and David Renald},
  title = {Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]},
  journal = {Advances in Materials},
  volume = {11},
  number = {4},
  pages = {85-93},
  doi = {10.11648/j.am.20221104.12},
  url = {https://doi.org/10.11648/j.am.20221104.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20221104.12},
  abstract = {Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C38H30N8)2•CoCl4] (1), crystallizes in the monoclinic space group P21/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å3. Compound [(CH3NH3)2•CoCl4] (2), crystallizes in the monoclinic space group P21/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å3. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R22(4), R34(10), R44(12), R55(14), R46(14), R56(16) and R66(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R21(4) rings and other hydrogen bonds of D type.},
 year = {2022}
}

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TY  - JOUR
T1  - Organic-Inorganic Hybrid Materials: Crystal Growth and XRD Analysis of [(C38H30N8)2•CoCl4] and [(CH3NH3)2•CoCl4]
AU  - Mouhamadou Birame Diop
AU  - Modou Sarr
AU  - Mouhamadou Sembene Boye
AU  - Sérigne Cissé
AU  - Libasse Diop
AU  - Allen G. Oliver
AU  - David Renald
Y1  - 2022/10/30
PY  - 2022
N1  - https://doi.org/10.11648/j.am.20221104.12
DO  - 10.11648/j.am.20221104.12
T2  - Advances in Materials
JF  - Advances in Materials
JO  - Advances in Materials
SP  - 85
EP  - 93
PB  - Science Publishing Group
SN  - 2327-252X
UR  - https://doi.org/10.11648/j.am.20221104.12
AB  - Two tetrachloridocobaltate (II) hybrid compounds were isolated and structurally characterized by single crystal X-ray crystallography. The compound [(C38H30N8)2•CoCl4] (1), crystallizes in the monoclinic space group P21/c with Z = 4, a = 12.0894(7) Å, b = 15.1839(8) Å, c = 19.8015(11) Å, β = 90.786(2)° and V = 3634.5(3) Å3. Compound [(CH3NH3)2•CoCl4] (2), crystallizes in the monoclinic space group P21/c with Z = 4, a = 7.6385(5) Å, b = 12.6684(8) Å, c = 10.8730(6) Å, β = 96.540(2)° and V = 1045.31(11) Å3. The compound 1 consists of 2,3,5-triphenyltetrazolium cations and tetrachloridocobaltate (II) ions connected through weak C-H•••Cl hydrogen bonds affording a 3D structure. Additional π•••π interactions consolidate the stability and the compactness of the 3D framework. The tetrazolium (C1N1N2N3N4) ring forms dihedral angles of 85.04(11), 49.37(11) and 27.85(11)° with the planes of the benzene rings of the substituent groups while the tetrazolium (C20N5N6N7N8) ring forms dihedral angles of 52.92(11), 47.37(11) and 9.97(11)° with the planes of the benzene rings of the substituent groups. The compound 2 is composed of methylammonium cations and tetrachloridocobaltate (II) dianions connected by extended N-H•••Cl hydrogen bonding patterns giving rise to a 3D structure. The methylammonium cations adopt a general position and are not exceptional. In both structures, the Co centre within the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The extensive hydrogen bonding patterns within compound 2 describe R22(4), R34(10), R44(12), R55(14), R46(14), R56(16) and R66(18) rings whereas 1, through the weak C-H•••Cl hydrogen bond patterns, generates mainly R21(4) rings and other hydrogen bonds of D type.
VL  - 11
IS  - 4
ER  -

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