Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils

Safarov Jasur; Khayitov Ruslan

doi:doi:10.11648/j.ogce.20221004.12

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Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils

Safarov Jasur, Khayitov Ruslan

Published in International Journal of Oil, Gas and Coal Engineering (Volume 10, Issue 4)

Received: 18 April 2022 Accepted: 15 September 2022 Published: 27 September 2022

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Abstract

The sorption capacity of the selected adsorbents was determined - silica gel CSL (coarse-pored silica gel lump) and synthetic zeolite CaA according to the standards of aromatic and n-paraffin hydrocarbons using the cryoscopic method. The amount of adsorbed substance in weight percent for each portion of the filtrate is converted into grams, summed up and referred to 100 g of the adsorbent. After that, the silica gel was washed with distilled water until the reaction to the Cl– ion was negative, unloaded onto filtered paper, and left to dry in the open air. The solution was passed in a chromatographic column through an adsorbent. The amount of adsorbed substance A was calculated. Type A synthetic zeolites include zeolites with radii: KA (0,3 nm), NaA (0,4 nm) and CaA (0,49 nm). CaA zeolite adsorbs hydrocarbons and alcohols of normal structure only (regardless of the chain length) due to the size of the input window corresponding to the size of their critical diameters The synthesized zeolites are powders and in order to use them under dynamic conditions, they are granulated with the addition of a binder, usually natural clays, and molded into tablets, cylinders, or balls. The sorption capacity of the synthetic zeolite CaA for n-hexane from the liquid phase under dynamic conditions is given. As can be seen from the given data, benzene is practically not adsorbed by CaA zeolite, but is adsorbed by silica gel. Moreover, CSL silica gel activated with hydrochloric acid has a higher capacity.

Published in	International Journal of Oil, Gas and Coal Engineering (Volume 10, Issue 4)
DOI	10.11648/j.ogce.20221004.12
Page(s)	97-100
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Aromatic Hydrocarbons, n-paraffin Hydrocarbons, n-hexane, Benzene, Cyclohexane, Adsorbent, Silica GEL, Brigleb-Stuart Models

References

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[2]	Keltsev N. V. Fundamentals of adsorption technology. - M.: Higher school, 1976. - 448 p.
[3]	Narmetova G. R. Colloidal - chemical bases for the creation of polyphase sorbents for gas - liquid - solid phase chromatography. - Tashkent, 1993. - 38 p.
[4]	Khaitov R. R., Ismatov D., Narmetova G. R. Molecular - sieve effect of synthetic zeolite CaA on hydrocarbons // Current problems of innovative technologies of chemical, oil and gas processing and food industries: a collection of articles of the Republican Scientific and Technical Conference. - Tashkent-Kungirot, 2010. - 47-48 p.
[5]	Safarov J. A., Khayitov R. R., Murodov M. N., & Zhumaeva M. T. (2019). Complex processing of used motor oils to obtain valuable products. Theory and practice of modern science, (4), 201-206 p.
[6]	Safarov J. A., Bakieva, Sh. K., & Nurullaeva, Z. V. (2016). Technological schemes of dewaxing processes. Science and Education Today, 3 (4), 31-33.
[7]	Sharipova, S. F., & Safarov, J. A. (2021). Modern laboratory device for oil fractionation. Science and Education, 2 (3).
[8]	Hotamov, Q. S., & Safarov, J. A. (2021). Analysis of oil sludge processing methods. Science and Education, 2 (2).
[9]	Safarov, B. J., Safarov, J. A., & Zinatdinov, I. B. (2021). Hydroisomerization of 1-hexene in the presence of aluminosilicate catalysts containing nickel and nickel sulfide. Universum: Technical science, (6-4 (87)), 9-13p.
[10]	Safarov, J. A., & Khaitov, R. R. (2021). Study of physical and chemical properties and chemical composition of used motor oils. Universum: Engineering Sciences, 6-4 (87), 14-19 p.
[11]	Safarov J. A., Karshiev, Z. A., Khotamov, K. Sh., & Sharipova, S. F. (2021). FORMATION OF ACETYLENE AND ALKENE COMPOUNDS DURING OXIDATIVE DEHYDROGENATION OF BUTENES TO BUTADIENE. Universum: Engineering Sciences, 9-2 (90), 29-33 p.
[12]	Safarov J. A. Choice of Refining Method and Complex Processing of Used Oils to Obtain Valuable Products. EPRA International Journal of Multidisciplinary Research (IJMR), 75 p.
[13]	Akhadov, A. A. (2021). High-cetane diesel fuels from the southern Kulbeshkak as selected oil. Science and Education, 2 (12), 304-309 p.
[14]	Safarov J. A, Rustamovich, H. L., & Hoshim ugli, T. A. (2021, January). RESTORING THE QUALITY OF USED ENGINE OILS. In Euro-Asia Conferences (Vol. 1, No. 1, pp. 29-33).
[15]	Salimova, Z. S. (2021). Oxidative dehydrogenation of ethylbenzene. Universum: Engineering Sciences, (6-4), 47-49 p.

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APA Style

Safarov Jasur, Khayitov Ruslan. (2022). Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils. International Journal of Oil, Gas and Coal Engineering, 10(4), 97-100. https://doi.org/10.11648/j.ogce.20221004.12

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ACS Style

Safarov Jasur; Khayitov Ruslan. Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils. Int. J. Oil Gas Coal Eng. 2022, 10(4), 97-100. doi: 10.11648/j.ogce.20221004.12

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Safarov Jasur, Khayitov Ruslan. Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils. Int J Oil Gas Coal Eng. 2022;10(4):97-100. doi: 10.11648/j.ogce.20221004.12

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@article{10.11648/j.ogce.20221004.12,
  author = {Safarov Jasur and Khayitov Ruslan},
  title = {Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {10},
  number = {4},
  pages = {97-100},
  doi = {10.11648/j.ogce.20221004.12},
  url = {https://doi.org/10.11648/j.ogce.20221004.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20221004.12},
  abstract = {The sorption capacity of the selected adsorbents was determined - silica gel CSL (coarse-pored silica gel lump) and synthetic zeolite CaA according to the standards of aromatic and n-paraffin hydrocarbons using the cryoscopic method. The amount of adsorbed substance in weight percent for each portion of the filtrate is converted into grams, summed up and referred to 100 g of the adsorbent. After that, the silica gel was washed with distilled water until the reaction to the Cl– ion was negative, unloaded onto filtered paper, and left to dry in the open air. The solution was passed in a chromatographic column through an adsorbent. The amount of adsorbed substance A was calculated. Type A synthetic zeolites include zeolites with radii: KA (0,3 nm), NaA (0,4 nm) and CaA (0,49 nm). CaA zeolite adsorbs hydrocarbons and alcohols of normal structure only (regardless of the chain length) due to the size of the input window corresponding to the size of their critical diameters The synthesized zeolites are powders and in order to use them under dynamic conditions, they are granulated with the addition of a binder, usually natural clays, and molded into tablets, cylinders, or balls. The sorption capacity of the synthetic zeolite CaA for n-hexane from the liquid phase under dynamic conditions is given. As can be seen from the given data, benzene is practically not adsorbed by CaA zeolite, but is adsorbed by silica gel. Moreover, CSL silica gel activated with hydrochloric acid has a higher capacity.},
 year = {2022}
}

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TY  - JOUR
T1  - Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils
AU  - Safarov Jasur
AU  - Khayitov Ruslan
Y1  - 2022/09/27
PY  - 2022
N1  - https://doi.org/10.11648/j.ogce.20221004.12
DO  - 10.11648/j.ogce.20221004.12
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 97
EP  - 100
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20221004.12
AB  - The sorption capacity of the selected adsorbents was determined - silica gel CSL (coarse-pored silica gel lump) and synthetic zeolite CaA according to the standards of aromatic and n-paraffin hydrocarbons using the cryoscopic method. The amount of adsorbed substance in weight percent for each portion of the filtrate is converted into grams, summed up and referred to 100 g of the adsorbent. After that, the silica gel was washed with distilled water until the reaction to the Cl– ion was negative, unloaded onto filtered paper, and left to dry in the open air. The solution was passed in a chromatographic column through an adsorbent. The amount of adsorbed substance A was calculated. Type A synthetic zeolites include zeolites with radii: KA (0,3 nm), NaA (0,4 nm) and CaA (0,49 nm). CaA zeolite adsorbs hydrocarbons and alcohols of normal structure only (regardless of the chain length) due to the size of the input window corresponding to the size of their critical diameters The synthesized zeolites are powders and in order to use them under dynamic conditions, they are granulated with the addition of a binder, usually natural clays, and molded into tablets, cylinders, or balls. The sorption capacity of the synthetic zeolite CaA for n-hexane from the liquid phase under dynamic conditions is given. As can be seen from the given data, benzene is practically not adsorbed by CaA zeolite, but is adsorbed by silica gel. Moreover, CSL silica gel activated with hydrochloric acid has a higher capacity.
VL  - 10
IS  - 4
ER  -

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Author Information

Safarov Jasur

Department of Oil Refining Technology, Bukhara Engineering-Technological Institute, Bukhara, Uzbekistan
Khayitov Ruslan

Department of Oil Refining Technology, Bukhara Engineering-Technological Institute, Bukhara, Uzbekistan

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APA Style

Safarov Jasur, Khayitov Ruslan. (2022). Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils. International Journal of Oil, Gas and Coal Engineering, 10(4), 97-100. https://doi.org/10.11648/j.ogce.20221004.12

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ACS Style

Safarov Jasur; Khayitov Ruslan. Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils. Int. J. Oil Gas Coal Eng. 2022, 10(4), 97-100. doi: 10.11648/j.ogce.20221004.12

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AMA Style

Safarov Jasur, Khayitov Ruslan. Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils. Int J Oil Gas Coal Eng. 2022;10(4):97-100. doi: 10.11648/j.ogce.20221004.12

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@article{10.11648/j.ogce.20221004.12,
  author = {Safarov Jasur and Khayitov Ruslan},
  title = {Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {10},
  number = {4},
  pages = {97-100},
  doi = {10.11648/j.ogce.20221004.12},
  url = {https://doi.org/10.11648/j.ogce.20221004.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20221004.12},
  abstract = {The sorption capacity of the selected adsorbents was determined - silica gel CSL (coarse-pored silica gel lump) and synthetic zeolite CaA according to the standards of aromatic and n-paraffin hydrocarbons using the cryoscopic method. The amount of adsorbed substance in weight percent for each portion of the filtrate is converted into grams, summed up and referred to 100 g of the adsorbent. After that, the silica gel was washed with distilled water until the reaction to the Cl– ion was negative, unloaded onto filtered paper, and left to dry in the open air. The solution was passed in a chromatographic column through an adsorbent. The amount of adsorbed substance A was calculated. Type A synthetic zeolites include zeolites with radii: KA (0,3 nm), NaA (0,4 nm) and CaA (0,49 nm). CaA zeolite adsorbs hydrocarbons and alcohols of normal structure only (regardless of the chain length) due to the size of the input window corresponding to the size of their critical diameters The synthesized zeolites are powders and in order to use them under dynamic conditions, they are granulated with the addition of a binder, usually natural clays, and molded into tablets, cylinders, or balls. The sorption capacity of the synthetic zeolite CaA for n-hexane from the liquid phase under dynamic conditions is given. As can be seen from the given data, benzene is practically not adsorbed by CaA zeolite, but is adsorbed by silica gel. Moreover, CSL silica gel activated with hydrochloric acid has a higher capacity.},
 year = {2022}
}

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TY  - JOUR
T1  - Determination of Sorption Capacity for Different Sorbates of Adsorbents Used for Dearomatization and Deparaffinization of Motor Oils
AU  - Safarov Jasur
AU  - Khayitov Ruslan
Y1  - 2022/09/27
PY  - 2022
N1  - https://doi.org/10.11648/j.ogce.20221004.12
DO  - 10.11648/j.ogce.20221004.12
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 97
EP  - 100
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20221004.12
AB  - The sorption capacity of the selected adsorbents was determined - silica gel CSL (coarse-pored silica gel lump) and synthetic zeolite CaA according to the standards of aromatic and n-paraffin hydrocarbons using the cryoscopic method. The amount of adsorbed substance in weight percent for each portion of the filtrate is converted into grams, summed up and referred to 100 g of the adsorbent. After that, the silica gel was washed with distilled water until the reaction to the Cl– ion was negative, unloaded onto filtered paper, and left to dry in the open air. The solution was passed in a chromatographic column through an adsorbent. The amount of adsorbed substance A was calculated. Type A synthetic zeolites include zeolites with radii: KA (0,3 nm), NaA (0,4 nm) and CaA (0,49 nm). CaA zeolite adsorbs hydrocarbons and alcohols of normal structure only (regardless of the chain length) due to the size of the input window corresponding to the size of their critical diameters The synthesized zeolites are powders and in order to use them under dynamic conditions, they are granulated with the addition of a binder, usually natural clays, and molded into tablets, cylinders, or balls. The sorption capacity of the synthetic zeolite CaA for n-hexane from the liquid phase under dynamic conditions is given. As can be seen from the given data, benzene is practically not adsorbed by CaA zeolite, but is adsorbed by silica gel. Moreover, CSL silica gel activated with hydrochloric acid has a higher capacity.
VL  - 10
IS  - 4
ER  -

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