International Journal of Nutrition and Food Sciences

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Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS

Received: Jun. 05, 2018    Accepted: Jun. 22, 2018    Published: Jul. 17, 2018
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Abstract

To establish the GPC - GC - MS detection method for determination of organochlorine pesticide residues in milk powder. After simple processing samples, concentration with multi-position concentrator, and online cleaning with GPC-GC-MS, injection into the mass spectrometer for analysis. Results showed that in the linear range of 5~100 ug/L, the correlation coefficient were >0.998, and the method detection limits (MDLs) were <0.5 ug/kg. The spiked recoveries at three levels of 10, 50, 100 ug/kg were in the range of 70 ~ 95%, the relative standard deviations (RSDs) (n=6) were<10%. This method had advantages of good accuracy and precision, simple operation, rapid, and was suitable for routine analysis.

DOI 10.11648/j.ijnfs.20180704.13
Published in International Journal of Nutrition and Food Sciences ( Volume 7, Issue 4, July 2018 )
Page(s) 129-133
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

GPC - GC – MS, Organochlorine, Pesticide Residues, Milk Powder

References
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[2] Wu minglai. Exploration of pretreatment methods for detection of organochlorine and pyrethroid pesticide residues in vegetables [J]. Anhui Agricultural Science Bulletin, 2012, 18 (13): 197~198.
[3] Liu Yi, Zheng Guocan, Wang Jing, et al. Determination of 20 Organochlorine Pesticides Residues in Milk by Gas Chromatography-Tandem Mass Spectrometry [J]. Journal of Inspection and Quarantine, 2012, 4 (22): 38~45.
[4] Deng Xiaojuan, Li Wenbin, Jin Lichuan, et al. Determination of 24 Organochlorine and Pyrethroid Pesticide Residues in Milk by Modified QuEChERS Method and Gas Chromatography [J]. Food Science, 2016, 18 (37): 141~145.
[5] GB/T 23210—2008, Determination of 511 pesticides and related chemicals residues in milk and milk powder GC-MS method [S].
[6] GB/T 23211-2008, Determination of 493 pesticides and related chemicals residues in milk and milk powder LC-MS-MS method [S].
[7] Yan Hui, Zhang Wen-li, Jiang Jia-xiao, et al. Determination of 20 organochlorine pesticides in soils using gas chromatography-tandem mass spectrometry combined with accelerated solvent extraction and gel permeation chromatography [J]. Chinese Journal of Analysis Laboratory, 2015, 34(6): 722~726.
[8] Su Jian-feng, Zhong Mao-sheng, Chen Jing, et al. Multi-residue Determination of 295 Pesticides in Tea and Its Products by Gas Chromatography-Mass Spectrometry and Gas Chromatography [J]. Journal of Instrumental Analysis, 2015, 34 (6): 625~638.
[9] Wang Bo, Li Xian-liang, Zhang Lei, et al. Simultaneous Determination of Organochlorine and Pyrethroid Pesticide Residues in Hotpot Condiment by Gas Chromatography [J]. Chinese Journal of Analytical Chemistry, 2010, 38 (10): 1433~1438.
[10] Zhang Yuan, Zhang Qi, Wang Xian-qin. SPE-GC/MS determination of 19 organophosphorus pesticide residues and organochlorine pesticide residues in Rhizoma Curcumae [J]. Chin J Pharm Anal, 2012, 32(1): 95~98.
[11] Fu Wenwen, Luo Tong, Zhu Ying, et al. Determination of Organochlorine Pesticides and Polychlorinated Biphenyls in Milk by QuEChERS-Gas Chromatography-Tandem Mass Spectrometry [J]. Food Science, 2018, 8(39): 309~313.
[12] Xue Haiquan, Cui Zhaojie, Du Shi-yong. Determination of organochlorine pesticides and polychlorinated biphenyls in wheat by gas chromatography with accelerated solvent extraction and gel permeation chromatography cleanup [J]. Journal of Shandong University (Natural Science), 2011, 46(1): 11~15.
[13] Du Juan, Lv Bing, Zhu Pan. et al. Determination of 30 organochlorine pesticides in animal-originated food products using combined purification by gel permeation chromatography and solid-phase extraction coupled with gas chromatography-mass spectrometry [J]. Chinese Journal of Chromatography, 2013, 31(8): 739~746.
[14] Chen Meiyu. Study and Application of Analytical Method for Pesticide Residue in Food by Gas Chromatography-Mass Spectrometry and Gas Chromatography-Tandem Mass Spectrometry [D]. Xiamen: Xiamen University, 2007.
[15] Zheng Junhong. Determination of multiple pesticides residue in milk and milk powder by LC-MS/MS [D]. Shandong: Shandong Agricultural University, 2009.
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    Zhaofeng Wu, Xiaoyan Peng, Sheng Chen, Zhanteng Zeng. (2018). Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS. International Journal of Nutrition and Food Sciences, 7(4), 129-133. https://doi.org/10.11648/j.ijnfs.20180704.13

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    ACS Style

    Zhaofeng Wu; Xiaoyan Peng; Sheng Chen; Zhanteng Zeng. Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS. Int. J. Nutr. Food Sci. 2018, 7(4), 129-133. doi: 10.11648/j.ijnfs.20180704.13

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    AMA Style

    Zhaofeng Wu, Xiaoyan Peng, Sheng Chen, Zhanteng Zeng. Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS. Int J Nutr Food Sci. 2018;7(4):129-133. doi: 10.11648/j.ijnfs.20180704.13

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  • @article{10.11648/j.ijnfs.20180704.13,
      author = {Zhaofeng Wu and Xiaoyan Peng and Sheng Chen and Zhanteng Zeng},
      title = {Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS},
      journal = {International Journal of Nutrition and Food Sciences},
      volume = {7},
      number = {4},
      pages = {129-133},
      doi = {10.11648/j.ijnfs.20180704.13},
      url = {https://doi.org/10.11648/j.ijnfs.20180704.13},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ijnfs.20180704.13},
      abstract = {To establish the GPC - GC - MS detection method for determination of organochlorine pesticide residues in milk powder. After simple processing samples, concentration with multi-position concentrator, and online cleaning with GPC-GC-MS, injection into the mass spectrometer for analysis. Results showed that in the linear range of 5~100 ug/L, the correlation coefficient were >0.998, and the method detection limits (MDLs) were <0.5 ug/kg. The spiked recoveries at three levels of 10, 50, 100 ug/kg were in the range of 70 ~ 95%, the relative standard deviations (RSDs) (n=6) were<10%. This method had advantages of good accuracy and precision, simple operation, rapid, and was suitable for routine analysis.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS
    AU  - Zhaofeng Wu
    AU  - Xiaoyan Peng
    AU  - Sheng Chen
    AU  - Zhanteng Zeng
    Y1  - 2018/07/17
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ijnfs.20180704.13
    DO  - 10.11648/j.ijnfs.20180704.13
    T2  - International Journal of Nutrition and Food Sciences
    JF  - International Journal of Nutrition and Food Sciences
    JO  - International Journal of Nutrition and Food Sciences
    SP  - 129
    EP  - 133
    PB  - Science Publishing Group
    SN  - 2327-2716
    UR  - https://doi.org/10.11648/j.ijnfs.20180704.13
    AB  - To establish the GPC - GC - MS detection method for determination of organochlorine pesticide residues in milk powder. After simple processing samples, concentration with multi-position concentrator, and online cleaning with GPC-GC-MS, injection into the mass spectrometer for analysis. Results showed that in the linear range of 5~100 ug/L, the correlation coefficient were >0.998, and the method detection limits (MDLs) were <0.5 ug/kg. The spiked recoveries at three levels of 10, 50, 100 ug/kg were in the range of 70 ~ 95%, the relative standard deviations (RSDs) (n=6) were<10%. This method had advantages of good accuracy and precision, simple operation, rapid, and was suitable for routine analysis.
    VL  - 7
    IS  - 4
    ER  - 

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Author Information
  • China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China

  • China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China

  • China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China

  • China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China

  • Section