This work focuses on the study of the adsorption of methylene blue (BM) and a green dye (CV) in aqueous solution by the pan bottom from a mining waste from Betaré-Oya. The aim is to recover mining waste as an adsorbent. The influence of physico-chemical parameters on the kinetics and isotherm of adsorption of these dyes on the pan bottom was determined. The UV/Visible spectroscopy technique was used for the analyses. The green dye was study at spectral wavelength 570 nm. Green. Adsorption equilibrium times are 15 minutes for these dyes. Experiments show that when the bottom mass of the pan increases, the quantities adsorbed decrease. In fact, it is the adsorption yields that increase from 60 to 80% for BM and from 30 to more than 90% for CV. Variations in pH showed greater adsorption of dyes in basic medium (pH ≥ 10) which indicates that the dyes are cationic. It was also observed that the amounts of BM and CV per unit of pan bottom increase with increasing initial concentration. The experimental data was analyzed by isotherm models. The value of the constant n of the Freundlich model for BM is 1.53, indicating that adsorption is unfavorable, whereas in the case of CV, adsorption is moderate. Langmuir and Temkin models better describe MB adsorption. The mechanism of adsorption of BM and CV is of chemical type. Pseudo-first-order, pseudo-second-order, Elovich and intra-particle kinetic models have been applied on data and the most suitable is the pseudo-second-order kinetic model.
| Published in | American Journal of Chemical Engineering (Volume 12, Issue 3) |
| DOI | 10.11648/j.ajche.20241203.13 |
| Page(s) | 65-71 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Adsorption, Pan Bottom, Dye, Isotherm Models, Kinetic Modelling, Water Treatment
| [1] | Fabre B., Ayelé J., Mazet M., Lafrance P., Adsorption du pentachlorophenol sur divers matériaux: Influence de co-adsorbats organiques (Substances humiques et lindane) [Adsorption of pentachlorophenol on various materials: In-fluence of organic co-adsorbates (humic substances and lindane)], Revue des sciences de l’eau, 90(3) (1990) P277-292. |
| [2] | Garg V. K., Gupta R., Juneja T., Removal of a Basic Dye (Rhodamine-B) From Aqueous Solution by Adsorption Using Timber Industry Waste, Chem. Biochem. Eng, 19(1) (2005) P75-80. |
| [3] | Ndi J. N., Ketcha M. J., The adsorption efficiency of chemically prepared activated carbon from cola nut shells by ZnCl2 on methylene blue, Journal of chemistry, ID469170, (2013) P7. |
| [4] | Dipa Ghosh., Krishna G., Bhattacharyya., Adsorption of méthylène blue on kaolinite Applied, Applied Clay Science, 20(2002) P295-300. |
| [5] | Gurusamy A., Lai Yiling., Jiunn-Fwu LEE., Adsorption of reactive dye from an aqueous solution by chitosan : isotherm, kinetic and thermodynamic analysis, Journal of Hazardous Materials, 152(1) (2008) P337-346. |
| [6] | Wang Li., Wang Aiqin., Adsorption properties of congo red from aqueous solution onto N, O-carboxymethyl-chitosan, Bioresource Technology, 99(2008) P1403-1408. |
| [7] | Ababou N., Meziane D., Kherbeche A., Chaqroune A., Etude de l'adsorption de colorants textiles surune diatomite marocaine [Study of the adsorption of textile dyes on a Moroccan diatomite], Phys. Chem. News 6(2002) P130-134. |
| [8] | Shin H. S., Lee J. K., Performance Evaluation of Electrocoagulation and Electrodewatering System for Reduction of Water Content in Sewage Sludge, Korean Chem Eng, 2(2006) P88-89. |
| [9] | Suksaroj Chaisri., Nanofiltration et oxydation avancée de solutions de colorants. Application au traitement d’effluents de l’industrie textiles [Nanofiltration and advanced oxidation of dye solutions. Application to effluent treatment in the textile industry], Thèse de doctorat, faculté des sciences, l’Université Montpellier II, (2006) P135. |
| [10] | Nozet H., Textiles chimiques. Fibres modernes [Chemical textiles. Modern fibers], Eyrolles, Paris, (1976). |
| [11] | Dali Youcef. L., purification et caractérisation de l’attapulgite Algérienne. Application à l’adsorption du bleu de methylene [Purification and characterization of Algerian attapulgite. Application to methylene blue adsorption], mémoire de magister., Faculté des sciences., Université d’Oran, (2012) P122. |
| [12] | Mouthe A. G. A., Măicăneanu A., Bike Mbah J. B., Ndjeumi C. C., Cotet L. C., Kamga R., 2016. Physico-chemical properties and crystal violet adsorption performances of H3PO4 - modified mango seeds kernel. Studia Universitatis Babes-Bolyai. Chemia, vol. 61, no. 3, Sept. 2016, pp. 195–214. |
| [13] | Mouthe A. G. A., Etude physicochimique de l’adsorption du crystal violet par le biosorbant et le charbon actif des amandes de mangue. Thèse de doctorat/PhD, ENSAI, université de Maroua, (2017) P 218. |
| [14] | Bouba. T., Adsorption du bleu de méthylène et de la tartrazine en milieu aqueuse par l’argile brute et l’argile pontée de boboyo [Adsorption of methylene blue and tartrazine in aqueous medium by raw clay and boboyo bridged clay], mémoire de master., faculté des sciences., université de Maroua, (2017) P77. |
| [15] | Bouacherine Souheila., Elimination des polluants spécifiques par adsorption sur charbon actif et argile traitée ou non traitée [Removal of specific pollutants by adsorption on activated carbon and treated or untreated clay], mémoire magister, faculté des sciences., Université Mohamed chérif Messaadia-Souk-Ahras, (2013) P137. |
| [16] | Zied Marzougui., Elaboration de latex magnétique fonctionnalisée pour le traitement des eaux usées par adsorption [Development of functionalized magnetic latex for adsorptive wastewater treatment], Doctorat en chimie, faculté des sciences, Université de claude Bernard Lyon 1, (2011) P228. |
| [17] | Emna Errais., Réactivité de surface d’argile naturelle : Etude de l’adsorption de colorants anioniques [Surface reactivity of natural clay: Study of the adsorption of anionic dyes], Thèse de doctorat, faculté des sciences Université de Strasbourg, Géochimie et environnement, (2011) P210. |
| [18] | Idris S., Yaka Y. A. I., Danda B. E. N., Ndamitso M. M., Umar M. T., Kinetic Study of Utilizing Groundnut Shell as an Adsorbent in Removing Chromium and Nickel from Dye Effluent, American Chemical Science journaL, 2(2012) P12-24. |
| [19] | Reddy D. H. K., Harinath Y., Seshaiah K., and Reddy A. V. R., Biosorption of Pb (II) from Aqueous Solution Using Chemically Modified Moringa Oleifera Tree Leaves, Chemical Engineering Journal, 162(2010) P626-634. |
| [20] |
Ndjeumi C. C., Măicăneanu A., Bike Mbah J. B., Mouthe A. G. A., Kamga R., 2015. Assessment of Physico-Chemical Parameters for Humic Acids Adsorption on Alumina. AIS-Chemistry Journal, Vol. 1, 4, 133-138.
http://files.aiscience.org/journal/article/html/70410024.html |
| [21] | Tomlinson A. G., Characterization of Pillared Layered Structure, Journal of porous materials, 5(2005) P259-274. |
| [22] | Belaid K. D., Kacha S., Etude Cinétique et Thermodynamique de l’Adsorption d’un Colorant Basique [Kinetic and Thermodynamic Study of Adsorption of a Basic Dye], Revue des Sciences de l’Eau, (2011) P131-144. |
| [23] | Nadeen M., Mahmood A., Shahid S. A., Shah S. S., Khalid A. M., and Mackay G. M., Sorption of Lead From Aqueous Solution by Chemically Modified Carbon Adsorbent, Journal of Hazardous Materials, 138(2006) P604-613. |
| [24] | Dobé Narcisse., Adsorption de la carmoisine et du cristal violet en solution aqueuse par l’argile de boboyo [Adsorption of carmoisine and crystal violet in aqueous solution by boboyo clay], Mémoire master, Faculté des sciences., Université de Maroua, (2018) P94. |
| [25] | Noureddine BARKA., Etude comparative des propriétés d’adsorption de quelques micro-polluants sur les phosphates naturels et le charbon actif [Comparative study of adsorption properties of some micro-pollutants on rock phosphates and activated carbon], Diplôme d’études Supérieures Approfondies de l’université IBN ZOHR, Agadir (Maroc), (2004) P45. |
| [26] | Gaineunbo., adsorption du bleu de méthylène et du méthyle orange en solution aqueuse par le charbon actif issus des coques de Vitex doniana [adsorption of methylene blue and methyl orange in aqueous solution by activated carbon from Vitex doniana shells], Mémoire de master, Faculté des sciences, université de Ngaoundéré, (2013) P89. |
| [27] | Bouanimba N., Modélisation et Optimisation de la Cinétique de Degradation Photocatalytique de Polluants Organiques en Solution Aqueuse [Modeling and Optimization of the Photocatalytic Degradation Kinetics of Organic Pollutants in Aqueous Solution], Master en Chimie, Faculté des Sciences, Université Mentouri-Constantine, (2009) P195. |
APA Style
Atchana, J., Ndjeumi, C. C., Ngalda, M. (2024). Assessment of Removal Methylene Blue and Green Dye in Water by Adsorption in Aqueous Solution by the Pan Bottom from a Mining Waste from Betaré-Oya. American Journal of Chemical Engineering, 12(3), 65-71. https://doi.org/10.11648/j.ajche.20241203.13
ACS Style
Atchana, J.; Ndjeumi, C. C.; Ngalda, M. Assessment of Removal Methylene Blue and Green Dye in Water by Adsorption in Aqueous Solution by the Pan Bottom from a Mining Waste from Betaré-Oya. Am. J. Chem. Eng. 2024, 12(3), 65-71. doi: 10.11648/j.ajche.20241203.13
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Download@article{10.11648/j.ajche.20241203.13,
author = {Jeanne Atchana and Chrisdel Chancelice Ndjeumi and Moutsina Ngalda},
title = {Assessment of Removal Methylene Blue and Green Dye in Water by Adsorption in Aqueous Solution by the Pan Bottom from a Mining Waste from Betaré-Oya
},
journal = {American Journal of Chemical Engineering},
volume = {12},
number = {3},
pages = {65-71},
doi = {10.11648/j.ajche.20241203.13},
url = {https://doi.org/10.11648/j.ajche.20241203.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20241203.13},
abstract = {This work focuses on the study of the adsorption of methylene blue (BM) and a green dye (CV) in aqueous solution by the pan bottom from a mining waste from Betaré-Oya. The aim is to recover mining waste as an adsorbent. The influence of physico-chemical parameters on the kinetics and isotherm of adsorption of these dyes on the pan bottom was determined. The UV/Visible spectroscopy technique was used for the analyses. The green dye was study at spectral wavelength 570 nm. Green. Adsorption equilibrium times are 15 minutes for these dyes. Experiments show that when the bottom mass of the pan increases, the quantities adsorbed decrease. In fact, it is the adsorption yields that increase from 60 to 80% for BM and from 30 to more than 90% for CV. Variations in pH showed greater adsorption of dyes in basic medium (pH ≥ 10) which indicates that the dyes are cationic. It was also observed that the amounts of BM and CV per unit of pan bottom increase with increasing initial concentration. The experimental data was analyzed by isotherm models. The value of the constant n of the Freundlich model for BM is 1.53, indicating that adsorption is unfavorable, whereas in the case of CV, adsorption is moderate. Langmuir and Temkin models better describe MB adsorption. The mechanism of adsorption of BM and CV is of chemical type. Pseudo-first-order, pseudo-second-order, Elovich and intra-particle kinetic models have been applied on data and the most suitable is the pseudo-second-order kinetic model.
},
year = {2024}
}
TY - JOUR T1 - Assessment of Removal Methylene Blue and Green Dye in Water by Adsorption in Aqueous Solution by the Pan Bottom from a Mining Waste from Betaré-Oya AU - Jeanne Atchana AU - Chrisdel Chancelice Ndjeumi AU - Moutsina Ngalda Y1 - 2024/06/27 PY - 2024 N1 - https://doi.org/10.11648/j.ajche.20241203.13 DO - 10.11648/j.ajche.20241203.13 T2 - American Journal of Chemical Engineering JF - American Journal of Chemical Engineering JO - American Journal of Chemical Engineering SP - 65 EP - 71 PB - Science Publishing Group SN - 2330-8613 UR - https://doi.org/10.11648/j.ajche.20241203.13 AB - This work focuses on the study of the adsorption of methylene blue (BM) and a green dye (CV) in aqueous solution by the pan bottom from a mining waste from Betaré-Oya. The aim is to recover mining waste as an adsorbent. The influence of physico-chemical parameters on the kinetics and isotherm of adsorption of these dyes on the pan bottom was determined. The UV/Visible spectroscopy technique was used for the analyses. The green dye was study at spectral wavelength 570 nm. Green. Adsorption equilibrium times are 15 minutes for these dyes. Experiments show that when the bottom mass of the pan increases, the quantities adsorbed decrease. In fact, it is the adsorption yields that increase from 60 to 80% for BM and from 30 to more than 90% for CV. Variations in pH showed greater adsorption of dyes in basic medium (pH ≥ 10) which indicates that the dyes are cationic. It was also observed that the amounts of BM and CV per unit of pan bottom increase with increasing initial concentration. The experimental data was analyzed by isotherm models. The value of the constant n of the Freundlich model for BM is 1.53, indicating that adsorption is unfavorable, whereas in the case of CV, adsorption is moderate. Langmuir and Temkin models better describe MB adsorption. The mechanism of adsorption of BM and CV is of chemical type. Pseudo-first-order, pseudo-second-order, Elovich and intra-particle kinetic models have been applied on data and the most suitable is the pseudo-second-order kinetic model. VL - 12 IS - 3 ER -
Department of Chemical Engineering, Higher Technical Teacher’s Training Colleg, University of Douala, Douala, Cameroon
Department of Environmental Sciences, National Advanced School of Engineering of Maroua, The University of Maroua, Maroua, Cameroon
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