The results of studies of the cooling ability, rheological and surface-active properties of aqueous solutions of polyalkyleneglycol, sodium salt of carboxymethyl cellulose and polyacrylamide are presented. The choice of polymers is due to the problem of studying the mechanism of the cooling process in aqueous solutions of polymers. Comparison of the results of complex studies and video surveillance made it possible to propose a substantiated version of the mechanism of heat transfer during cooling of a metal sample in aqueous solutions of polymers. At the moment of shock boiling, a substance is formed in the wall layer, which is a nanosol (for PAG solutions) or a nanogassuspension (for Na-CMC and PAA). Under the action of a shock wave, it is directed from the heated metal surface to the interface between the polymer solution-vapor film, forming an interfacial polymer shock film. One of the stages of the shock mechanism of the formation of a polymer film is the adsorption increase in the polymer concentration on the surface of the bubbles formed during shock boiling; the next stage, the polymer shell of the bubbles, is spent on the formation of an interfacial polymer film. Heat fluxes and heat transfer coefficients are presented as a function of polymer concentration and surface temperature. The research results can be useful for assessing the effect of an interfacial polymer film on the ratio of the initial, first qcr1 and second qcr2 critical heat fluxes density, which determines the passage of heat transfer stages in water-polymer quenching media (WPQM).
| Published in | International Journal of Fluid Mechanics & Thermal Sciences (Volume 6, Issue 4) |
| DOI | 10.11648/j.ijfmts.20200604.12 |
| Page(s) | 108-123 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2020. Published by Science Publishing Group |
Aqueous Quenchants, Impact Mechanism, Interfacial Polymer Film, Chock Film Boiling
| [1] | Kobasko N. I., Shvets Yu. I., Fialko N. M., Meranova N. O., Nikolaev E. D. Cooling capacity of an aqueous solution of PK-2 polymer at different temperatures. Metallurgy and heat treatment of metals. 1985. No. 9. pp. 2-5. |
| [2] | Kobasko N. I., Timchenko N. G. A cinematic study of the cooling process of samples in aqueous polymer solutions. MiTOM, 1986. No. 10, pp. 25-29. |
| [3] | Kobasko N. I. Increasing the service life of machine parts and tools by intensifying their cooling during quenching. MiTOM, 1986. No. 10, pp. 47-52. |
| [4] | Tensi H. M., Stitzelberger J. P. Influence of rewetting on hardening processes // Industrial heat engineering. 1989.-11, No. 4, pp. 57-66. |
| [5] | Kobasko N. I. Technological aspects of cooling during quenching (review). MITOM, 1991. No. 4. pp. 2-8. |
| [6] | Kobasko N. I., Krivoshey F. A. On the mechanism of temperature and heat flux fluctuations during cooling of metal samples in aqueous solutions of polymers. Reports of the Academy of Sciences of Ukraine. 1994. No. 11. pp. 90-94. |
| [7] | Kobasko N. I., Moskalenko A. A. Intensification of hardening methods by using aqueous polymer solutions. Industrial heating technology. 1996. No. 6. pp. 55-60. |
| [8] | Moskalenko A. A., Kobasko N. I., Tolmacheva O. V., Totten G. T., Webster G. M. (1996) Quenchants Characterization by Acoustical Noise Analysis of Cooling Properties of Aqueous Poly (Alkylene Glycol) Polymer Quenchants. Proc. of the 2nd Int. Conf. on Quenching and Control of the Distortion. (USA). pp. 117-122. |
| [9] | Waldeck S., Castens M., Riefler N., Frerichs F., Lubben Th. and Fritsching U. HTM Journal of Heat Treatment and Materials, 2019, 74, 4, p. 238-256. |
| [10] | G. V. Kovalenko, N. I. Kobasko Simulation of unsteady boiling during quenching cooling in water. Industrial heating technology. 1986, T. 8, No. 6, pp. 29-35. |
| [11] | Mikita Y., Nakabayashi I., Ohga N., and Ohsaka K. Hippon Kikai Gakkai Ronbunshu (A-hen). Vol 53 (No. 496).1987. pp. 2211-2215. |
| [12] | Nikolaev A. F., Okhrimenko G. I. Water-soluble polymers. -L.: Chemistry, 1979.-144p. |
| [13] | Lipatov Yu. S., Sergeeva L. M. Adsorption of polymers. Naukova Dumka. Kiev. -1972.-195p. |
| [14] | Privalko V. P., Novikov V. V., Yanovskiy Yu. G. Fundamentals of Thermophysics and Rheophysics of Polymeric Materials. Kiev: Naukova Dumka, -1991.-232p. |
| [15] | Totten G. E. Polymer Quenchants for Induction Heat Treating Applications: The Basics. In 9th International Induction Heat Treating Seminar, FL, May 2000. https://www.researchgate.net/publication/228480536. |
| [16] | Kobacko N. I., Real and Effective Heat Transfer Coefficients (NTCs) Used for Computer Simulayion of Transient Nucleate Boiling Processes During Quenching Materials Performance and Characterization, 2012, Vol. 1, No. 1, pp. 1-20. |
| [17] | Zordao L. P., Oliveria V. A., Totten G. E., Canale L. C. F. Quenching Power of Aqueous Salt Solution., International Journal of Heat and Mass Transfer, 140 (2019), p. 807-818. |
| [18] | https://www.xumuk.ru/spravochnik/329.html. |
| [19] | Madorsky S. L. Thermal Degradation of Organic Polymers. -New York-London-Sydney. 1964.-351p. |
| [20] | Lohvynenko P. N., Moskalenko A. A., Kobasko N. I., Karsim L. O., Riabov S. V. Experimental Investigation of Effect of Polyisobutilene Additives to Mineral Oil on Cooling Characteristics. Materials Performance and Characterization. 2016, 5 (1), pp. 1-13. |
| [21] | Gul V. E., Kuleznev V. N. Structure and mechanical properties of polymers. M.: "High school", 1972.-320p. |
| [22] | Tager A. A. Physicochemistry of polymers. M., Goskhimizdat. 1963.-528p. |
| [23] | Tkachuk T. I., Rudakova N. Ya., Sheremet B. K., Novoded R. D. Possible Ways to Reduce the Film Boiling Period when Quenching in Petroleum Oils. Metallurgy and Heat Treatment of Metals. 1986, No. 10. pp. 42-44. |
| [24] | Faynerman A. E., Lipatov Yu. S., Kulik V. M., Vologina L. N., Simple Metnod for Determination of the Surface Tension and Contact Angler of Wetting of Liquids. Colloid journal. 1970. T. XXXII. No. 4. pp. 620-623. |
| [25] | Ramesh, G., Narayan Prabhu, K. (2016). Effect of Polymer Concentration on Wetting and Cooling Performance During Immersion Quenching. Metall and Materi Trans B 47, pp. 859-881. |
| [26] | Mathews N. D., Rao K. M. P., Nayak V., Prabhu K. N. Comparison of Cooling Behaviors of Carbon Steels in Polymer, Oil and Carbonated Quench. Media. Trans actions of the Indian Institute of Metals. January 2019. P. 1-6. |
| [27] | Onan M., Unan H. I., Onan C., Atapek I. Y. (2014). Understanding of Polymer Quenchants (Polyalkyleneglycol) Characteristic During Quenching Process of Tool Steels. International Journal Microstructure and Materials Properties, V. 9, No. 1, pp. 71-78. |
| [28] | Kobasco N. I. Steel Quenching in Liquid Media Under Pressure. Naukova Dumka, Kyiv, 1980-.216p. |
| [29] | Batte A. D., Marfi M. K., Fishe K. et al. Industrial heat treatment of steam turbine rotors made of chromium-molybdenum-vanadium steels. Ferrous metallurgy. 1979. No. 18. Pp. 14-19. |
| [30] | Okhrimenko T. V., Kuznetsov I. B., Lanin A. A. et al. Experience of hardening heat-resistant steels in a polymer environment based on Na-CMC. MiTOM, No. 4, 1991, p. 21-24. |
| [31] | Babu K., Prasanna Kumar T. S. Effect of CNT Concentration and Agitation on Surface Heat Flux During Quenching in CNT Nanofluids. International Journal of Heat Transfer, 2011, V. 54. pp. 106-117. |
| [32] | Shachneva Yu. Yu., Magomedova Z. A., Malagieva Kh. Z. Study of the physicochemical properties of carboxymethylcellulose (CMC) particles in aqueous solutions. Technique and technology of food production. 2014, No. 1, pp. 152-156. |
| [33] | Liscic B “Measurement and Recording of Quenching Intensity in Workshop Conditions Based on Temperature Gradients,” Materials Performance and Characterization, Vol. 5, No. 1. 2016. рр. 202-219. |
| [34] | Zotov E. N., Moskalenko A. A., Razumtseva O. V., Protsenko L. N., Dobrivecher V. V. Features of the Application of the IQLab Program for Solving the Inverse Problem of Heat Conduction for Chromium-Nickel Cylindrical Thermal Probes. Industrial Heat Engineering. 2018. Vol. 40, No. 3, pp. 91-96. |
| [35] | H. Polat, S. Chander Adsorption of PEO: PPO triblock co-polymers and wetting of coal / Colloids and Surfaces A: Physicochem. Eng. Aspects. -1999. V. 146. N 1-3.-p. 199-212. |
| [36] | Hernandez-Morales B., Vergara-Hernandez H. J., Solorio-Diaz G. and Totten G. E., Experimental and Computational Study of Heat Transfer During Quenching of Metallic Probes. Evaporation, Condensation and Heat transfer. September 12th 2011, DOI: 10.5772/24469. |
| [37] | Rudyak V. Ya., Belkin A. A. Modeling the transfer coefficients of nanofluids. Nanosystems: physics, chemistry, mathematics, 2010, Vol. 1, No. 1, pp. 156-177. |
| [38] | Kobasko N. Research on New Ways of Decreasing Distortion of Steel Parts During Hardening in Liquid Media. Asian Journal of Science and Technology Vol. 08, Issue, 08, pp. 5299-5304, August, 2017. |
| [39] | Kobasko N., Moskalenko A., Dobryvechir V. Research on Use of Low Concentration Inverse Solubility Polymers in Water for Hardening Machine Components and Tools. "EUREKA: Physics and Engineering", 2018, No. 2, pp. 63-71. |
| [40] | Kobasko N. I., Intensive steel quenching processes taking place in liquid media that are considered from the point of view of modern physics. International Journal of Physics and Applications. V. 1, Issue 2, 2019, pp. 16-26. |
| [41] | Kobasko N. I., Uniform and Intense Cooling During Hardening Steel in Low Concentration of Water Polymer Solutions. American Journal of Modern Physics, V. 8, No. 6, 2019, pp. 76-85. |
| [42] | Tsukrov S. L., Komov V. I., Mirzabekova N. S. Water-polymer quenching medium Laprol-ZS. MITOM, No. 4, 1993, pp. 5-7. |
| [43] | Belanov A. A., Kutyev A. P., Mirzabekova N. S. and other Research of polymer hardening environment ZAK-PG. MiTOM, No. 2, 1999, pp. 7-11. |
| [44] | Goryushin V. V., Shevchenko S. Yu. On the use of polymer quenching media in industry. MITOM, No. 6, 2010, p. 26-30. |
| [45] | Logvynenko P. N., Moskalenko A. A., Kobasko N. I., Razumtseva O. V., Karsim L. O. and Riabov S. V. Oligomeric Mechanism of Film Boilimg Elimination (EFB Effect) During Metal Quenching in Solutions of Polyisobutylene in Mineral Oil. International Journal of Current Research Vol. 11, Issue, 09, pp. 7333-7339, September, 2019. |
APA Style
Logvynenko Peter, Moskalenko Anatoly. (2020). Impact Mechanism of Interfacial Polymer Film Formation in Aqueous Quenchants. International Journal of Fluid Mechanics & Thermal Sciences, 6(4), 108-123. https://doi.org/10.11648/j.ijfmts.20200604.12
ACS Style
Logvynenko Peter; Moskalenko Anatoly. Impact Mechanism of Interfacial Polymer Film Formation in Aqueous Quenchants. Int. J. Fluid Mech. Therm. Sci. 2020, 6(4), 108-123. doi: 10.11648/j.ijfmts.20200604.12
AMA Style
Logvynenko Peter, Moskalenko Anatoly. Impact Mechanism of Interfacial Polymer Film Formation in Aqueous Quenchants. Int J Fluid Mech Therm Sci. 2020;6(4):108-123. doi: 10.11648/j.ijfmts.20200604.12
Share This Article
Twitter
Linked In
Facebook
Copy
Download@article{10.11648/j.ijfmts.20200604.12,
author = {Logvynenko Peter and Moskalenko Anatoly},
title = {Impact Mechanism of Interfacial Polymer Film Formation in Aqueous Quenchants},
journal = {International Journal of Fluid Mechanics & Thermal Sciences},
volume = {6},
number = {4},
pages = {108-123},
doi = {10.11648/j.ijfmts.20200604.12},
url = {https://doi.org/10.11648/j.ijfmts.20200604.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijfmts.20200604.12},
abstract = {The results of studies of the cooling ability, rheological and surface-active properties of aqueous solutions of polyalkyleneglycol, sodium salt of carboxymethyl cellulose and polyacrylamide are presented. The choice of polymers is due to the problem of studying the mechanism of the cooling process in aqueous solutions of polymers. Comparison of the results of complex studies and video surveillance made it possible to propose a substantiated version of the mechanism of heat transfer during cooling of a metal sample in aqueous solutions of polymers. At the moment of shock boiling, a substance is formed in the wall layer, which is a nanosol (for PAG solutions) or a nanogassuspension (for Na-CMC and PAA). Under the action of a shock wave, it is directed from the heated metal surface to the interface between the polymer solution-vapor film, forming an interfacial polymer shock film. One of the stages of the shock mechanism of the formation of a polymer film is the adsorption increase in the polymer concentration on the surface of the bubbles formed during shock boiling; the next stage, the polymer shell of the bubbles, is spent on the formation of an interfacial polymer film. Heat fluxes and heat transfer coefficients are presented as a function of polymer concentration and surface temperature. The research results can be useful for assessing the effect of an interfacial polymer film on the ratio of the initial, first qcr1 and second qcr2 critical heat fluxes density, which determines the passage of heat transfer stages in water-polymer quenching media (WPQM).},
year = {2020}
}
TY - JOUR T1 - Impact Mechanism of Interfacial Polymer Film Formation in Aqueous Quenchants AU - Logvynenko Peter AU - Moskalenko Anatoly Y1 - 2020/11/23 PY - 2020 N1 - https://doi.org/10.11648/j.ijfmts.20200604.12 DO - 10.11648/j.ijfmts.20200604.12 T2 - International Journal of Fluid Mechanics & Thermal Sciences JF - International Journal of Fluid Mechanics & Thermal Sciences JO - International Journal of Fluid Mechanics & Thermal Sciences SP - 108 EP - 123 PB - Science Publishing Group SN - 2469-8113 UR - https://doi.org/10.11648/j.ijfmts.20200604.12 AB - The results of studies of the cooling ability, rheological and surface-active properties of aqueous solutions of polyalkyleneglycol, sodium salt of carboxymethyl cellulose and polyacrylamide are presented. The choice of polymers is due to the problem of studying the mechanism of the cooling process in aqueous solutions of polymers. Comparison of the results of complex studies and video surveillance made it possible to propose a substantiated version of the mechanism of heat transfer during cooling of a metal sample in aqueous solutions of polymers. At the moment of shock boiling, a substance is formed in the wall layer, which is a nanosol (for PAG solutions) or a nanogassuspension (for Na-CMC and PAA). Under the action of a shock wave, it is directed from the heated metal surface to the interface between the polymer solution-vapor film, forming an interfacial polymer shock film. One of the stages of the shock mechanism of the formation of a polymer film is the adsorption increase in the polymer concentration on the surface of the bubbles formed during shock boiling; the next stage, the polymer shell of the bubbles, is spent on the formation of an interfacial polymer film. Heat fluxes and heat transfer coefficients are presented as a function of polymer concentration and surface temperature. The research results can be useful for assessing the effect of an interfacial polymer film on the ratio of the initial, first qcr1 and second qcr2 critical heat fluxes density, which determines the passage of heat transfer stages in water-polymer quenching media (WPQM). VL - 6 IS - 4 ER -
Information
Email: