The reagent (S)-5-methoxy-2-[[(4-methoxy-3, 5-dimethyl-2-pyridinyle-methyle] sulfinyle]-1H-benzimidazole gives greenish yellow coloration with V (V) as well as Co (II) in basic medium. This observation is used for the simultaneous determination of both the metal ions using Zero and second order derivative spectrophotometry. Optimum conditions were established for this determination. Job’s and mole-ratio methods are used for the determination of composition of the metal complexes. Determination of the metal ions was carried out in BAS alloys, and NTP ball bearings.
Published in | International Journal of Pharmacy and Chemistry (Volume 1, Issue 1) |
DOI | 10.11648/j.ijpc.20150101.11 |
Page(s) | 1-6 |
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Vanadium, Cobalt, ESMPZL, Derivative Spectrophotometry, Alloys, Steels and Synthetic Mixtures
[1] | Deaintith, J. Oxford Dictionary of Chemistry; Oxford University Press: Oxford, 1996; p 123. |
[2] | Filik H., Yanaz Z., A Sensitive Method for Determining Total Vanadium in Water Samples Using Colorimetric Solid Phase Extraction Fiber Optic Reflectance Spectroscopy, J. Hazard. Mater.,172, p. 1297 (2009). |
[3] | Filik H., Yanaz Z., Apak R., Selective Determination of Total Vanadium in Water Samples by Cloud Point Extraction of Its Ternary Complex, Anal. Chim.Acta, 620, p. 27 (2008). |
[4] | Bagherian G., Arab Chamjangali M., EskandariH.,Simultaneous Determination of Cobalt and Palladium in Micellar Media Using H-Point Standard Addition Method and Partial Least Square Regression, Spectrochim. Acta Part A, 67, p. 378 (2007). |
[5] | Abdollahi H., Zolgharnein J., AzimiG.H., JafarifarD., Simultaneous Spectrophotometric Determinationof Iron and Vanadium by H-Point Standard Addition Method and Partial Least Squares Regression inMicellar Medium, Talanta, 59, p. 1141 (2003). |
[6] | Verdu-Andres J., Bosch-Reig F., Campins-Falco P., H-point Standard Additions Methods forAnalyteDetermination in Ternary Mixtures, Analyst, 113, p. 1011 (1988). |
[7] | Afkhami A., Abbasi-Tarighat M., Bahram M., Abdollahi H., A New Strategy for Solving Matrix Effect in Multivariate Calibration Standard Addition Data Using Combination of H- Point Curve Isolation and H-Point Standard Addition Methods, Anal. Chim.Acta, 613, p. 144 (2008). |
[8] | Pouretedal H.R., Asefi M., H-point Standard Addition Method for Simultaneous Determination of Cobalt(II) and Zinc(II) Ions, J. Iran. Chem. Soc., 4, p. 503 (2007). |
[9] | Bosch-Reig F., Verdú-Andrés J., Campins-Falcó P.,MolinsLegua C., Study of the Behavior of theAbsorbent Blanks in Analytical Procedures by Using the H-Point Standard Addition Method (HPSAM),Talanta, 41, p. 39 (1994). |
[10] | Abdollahi H., Simultaneous Spectrophotometric Determination of Chromium (VI) and Iron (III) withChromogenic Mixed Reagents by H-Point Standard Addition Method and Partial Least Squares Regression, Anal. Chim. Acta, 442, p. 327 (2001). |
[11] | Afkhami A., ZareiA.R., Simultaneous Spectrophotometric Determination of Hydrazine and Pphenylhydrazine Media Using H-Point Standard Addition Method, Talanta, 62, p. 559 (2004). |
[12] | Campins-Falcó P., Verdú-Andrés J., Bosch-Reig F., Development of the H-Point Standard AdditionsMethod for the Use of Spectrofluorimetry and Synchronous Spectrofluorimetry, Analyst 119, p. 2123 (1994). |
[13] | Safavi A., Abdollahi H., Sedaghatpour F., Zeinali S., Kinetic Spectrophotometric Determination of V(IV) in the Presence of V(V) by the H-Point Standard Addition Method, Anal.Chim.Acta, 409, p. 275 (2000). |
[14] | Safavi A., Tohidi M., Simultaneous Kinetic Determination of Levodopa and Carbidopa by H-Point Standard Addition Method. J. Pharm. Biomed. Anal., 44, p. 313 (2007). |
[15] | Blasco-Gomez F., Campins-Falcó P., Bosch-Reig F., Molins-Legua C., Herráez-Hernández R., H-Point Curve Isolation Method for Coupled Liquid Chromatography and UV-Vis Spectrophotometry, Anal.Chem., 72, p. 2559 (2000). |
[16] | Campins-Falco P., Verdu-Andres J., Bosch-Reig F., MolinsLegua C., Generalized H-Point StandardAdditions Method for Analyte Determination in Unknown Samples, Anal.Chim. Acta, 302, p. 323 (1995). |
[17] | Campins-Falco P., Blasco-Gomez F., Bosch-Reig F., The H-Point and Generalized H-Point StandardAdditions Methods for Flow Injection Procedures, Talanta, 47, p. 193 (1998). |
[18] | Verdu-Andres J., Bosch-Reig F., Campins-Falco P., Analyte Estimation Using the Generalized H-Point Standard Additions Method and a New Methodology for Locating Linear Spectral Intervals for Unknown Interferents, J. Chemom., 12, p. 27 (1998). |
[19] | Blasco-Gomez F., Campins-Falco P., Molins-Llegua C., Herraez-hernandez R., H-Point CurveIsolation Method for Coupled Liquid Chromatography and UV-Visible Spectrophotometry, Anal. Chem. 72, p. 2559 (2000). |
[20] | S.N.Lanjwani and A.K.Chamer , Journal of Chromatographic, 1996, Vol-43, Issue 7- 8,431-432. |
[21] | T.Kiriyama and R.Kuroda Analyst Issue 1274, 1982, 505-510. |
[22] | Bing Chan and SandanobuInoue,Jouranal of Chromatographic Science, Vol 37, 1999. |
[23] | A. Praveen Kumar and V.Krishna Reddy, Journal of main group channel, ISSN, 1024-1221, 1745-1167, 2006. |
APA Style
B. Ranganath, P. Venkataramana, M. R. Jayapal. (2015). Simultaneous Determination of V (V) and Co (II) as (S)-5-Methoxy-2-[[(4-Methoxy-3, 5-Dimethyl-2-Pyridinyle-Methyle] Sulfinyle]-1H-Benzimidazole Using Derivative Spectrophotometry. International Journal of Pharmacy and Chemistry, 1(1), 1-6. https://doi.org/10.11648/j.ijpc.20150101.11
ACS Style
B. Ranganath; P. Venkataramana; M. R. Jayapal. Simultaneous Determination of V (V) and Co (II) as (S)-5-Methoxy-2-[[(4-Methoxy-3, 5-Dimethyl-2-Pyridinyle-Methyle] Sulfinyle]-1H-Benzimidazole Using Derivative Spectrophotometry. Int. J. Pharm. Chem. 2015, 1(1), 1-6. doi: 10.11648/j.ijpc.20150101.11
AMA Style
B. Ranganath, P. Venkataramana, M. R. Jayapal. Simultaneous Determination of V (V) and Co (II) as (S)-5-Methoxy-2-[[(4-Methoxy-3, 5-Dimethyl-2-Pyridinyle-Methyle] Sulfinyle]-1H-Benzimidazole Using Derivative Spectrophotometry. Int J Pharm Chem. 2015;1(1):1-6. doi: 10.11648/j.ijpc.20150101.11
@article{10.11648/j.ijpc.20150101.11, author = {B. Ranganath and P. Venkataramana and M. R. Jayapal}, title = {Simultaneous Determination of V (V) and Co (II) as (S)-5-Methoxy-2-[[(4-Methoxy-3, 5-Dimethyl-2-Pyridinyle-Methyle] Sulfinyle]-1H-Benzimidazole Using Derivative Spectrophotometry}, journal = {International Journal of Pharmacy and Chemistry}, volume = {1}, number = {1}, pages = {1-6}, doi = {10.11648/j.ijpc.20150101.11}, url = {https://doi.org/10.11648/j.ijpc.20150101.11}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijpc.20150101.11}, abstract = {The reagent (S)-5-methoxy-2-[[(4-methoxy-3, 5-dimethyl-2-pyridinyle-methyle] sulfinyle]-1H-benzimidazole gives greenish yellow coloration with V (V) as well as Co (II) in basic medium. This observation is used for the simultaneous determination of both the metal ions using Zero and second order derivative spectrophotometry. Optimum conditions were established for this determination. Job’s and mole-ratio methods are used for the determination of composition of the metal complexes. Determination of the metal ions was carried out in BAS alloys, and NTP ball bearings.}, year = {2015} }
TY - JOUR T1 - Simultaneous Determination of V (V) and Co (II) as (S)-5-Methoxy-2-[[(4-Methoxy-3, 5-Dimethyl-2-Pyridinyle-Methyle] Sulfinyle]-1H-Benzimidazole Using Derivative Spectrophotometry AU - B. Ranganath AU - P. Venkataramana AU - M. R. Jayapal Y1 - 2015/07/08 PY - 2015 N1 - https://doi.org/10.11648/j.ijpc.20150101.11 DO - 10.11648/j.ijpc.20150101.11 T2 - International Journal of Pharmacy and Chemistry JF - International Journal of Pharmacy and Chemistry JO - International Journal of Pharmacy and Chemistry SP - 1 EP - 6 PB - Science Publishing Group SN - 2575-5749 UR - https://doi.org/10.11648/j.ijpc.20150101.11 AB - The reagent (S)-5-methoxy-2-[[(4-methoxy-3, 5-dimethyl-2-pyridinyle-methyle] sulfinyle]-1H-benzimidazole gives greenish yellow coloration with V (V) as well as Co (II) in basic medium. This observation is used for the simultaneous determination of both the metal ions using Zero and second order derivative spectrophotometry. Optimum conditions were established for this determination. Job’s and mole-ratio methods are used for the determination of composition of the metal complexes. Determination of the metal ions was carried out in BAS alloys, and NTP ball bearings. VL - 1 IS - 1 ER -