This study investigated the effectiveness of single and mixed collectors in enhancing the flotation efficiency of low-grade coal from the Gamo region of Ethiopia, focusing on recovery rates and ash content. The research aimed to address the challenges posed by high ash content and impurities in Ethiopian coal, which limit the industrial application. Through controlled laboratory experiments, the performance of single collectors (kerosene, diesel oil, and oleic acid) and mixed collectors in varying dosages was evaluated. The Finding revealed distinct performance characteristics among the collectors. Kerosene demonstrated higher recovery rates (33.7%) but moderate ash content (27.2%), while oleic acid prioritized purity (lowest ash content of 24.9%) at the expense of recovery (27.3%). Diesel oil showed intermediate results. Mixed collector formulations further highlighted the trade-off between recovery and ash content. For instance, the balanced triple-mixed collector C13 (kerosene, oleic acid, and diesel oil in equal parts) achieved a competitive recovery rate of 55.2% with acceptable ash levels (33.7%). In contrast, formulations with higher oleic acid content (C11) yielded the lowest ash content (32%) but reduced recovery (44%). The study underscored the inverse relationship between recovery and ash content, emphasizing the need for tailored collector blends based on specific industrial priorities. For yield-focused processes, Diesel-rich blends like C10 (56.3% recovery) are recommended, while purity-focused applications benefit from oleic acid-dominant mixtures like C11. The balanced C13 formulation emerged as a practical choice for scenarios requiring a middle ground.
| Published in | International Journal of Oil, Gas and Coal Engineering (Volume 13, Issue 4) |
| DOI | 10.11648/j.ogce.20251304.11 |
| Page(s) | 55-69 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2025. Published by Science Publishing Group |
Single Collector, Mixed Collector, Floatation, Ash Content, Grade, Recovery
| [1] | Aman Yismaw, Bezayit Mitiku, Tesfaye G/Tsadik. 2015. “Basic Geoscience Mapping Directorate Geology Geochemistry and Gravity Survey of Sede Area.” Geology, Geochemistry and Gravity Survey of Dilla Mapsheet. (October). |
| [2] | Chinweze, Arinze, Akuchi Ikenna Joshua, Victor Chimdike Obinani, and C C Okunna. 2023a. “An Examination of Coal as an Energy Source.” Global Scientific Journals 11(4). |
| [3] | Chinweze, Arinze, Akuchi Ikenna Joshua, Victor Chimdike Obinani, and C C Okunna. 2023b. “An Examination of Coal as an Energy Source.” Global Scientific Journals 11(4): 69-81. |
| [4] | Crossley, Penelope. 2020. “From Coal to Clean Energy.” Routledge Handbook of Energy Law (April): 393-413. |
| [5] | Dejen, Awlachew, Sandeep Soni, and Fisha Semaw. 2019. “Remote Sensing Applications : Society and Environment Spatial Accessibility Analysis of Healthcare Service Centers in Gamo Gofa Zone, Ethiopia through Geospatial Technique.” Remote Sensing Applications: Society and Environment 13: 466-73. |
| [6] | Demirbas, M. F. 2007. “Progress of Fossil Fuel Science.” Energy Sources, Part B: Economics, Planning and Policy 2(3): 243-57. |
| [7] | Ding, Li Ping. 2010. “Effect of Collector Interfacial Tension on Coal Flotation of Different Particle Sizes.” Industrial & Engineering Chemistry Research 49(8): 3769-75. |
| [8] | Dwari, R. K., and K. Hanumantha Rao. 2007. “Dry Beneficiation of Coal - A Review.” Mineral Processing and Extractive Metallurgy Review 28(3): 177-234. |
| [9] | Endale Tabogie, Million Tadesse, Gizachew Welde Michael. 2003. “Enset-Based Farming Systems of Kucha Wereda Gamo Gofa Zone.” Ethiopian Agricultural Organization, SNNPR Agricultural Research Institute. |
| [10] | Gui, Xiahui, Yaowen Xing, Tingxia Wang, Yijun Cao, Zhenyong Miao, and Mengdi Xu. 2017. “Intensification Mechanism of Oxidized Coal Flotation by Using Oxygen-Containing Collector α-Furanacrylic Acid.” Powder Technology 305: 109-16. |
| [11] | Jaiswal, Soni, Sunil Kumar Tripathy, and P K Banerjee. 2015. “An Overview of Reverse Fl Otation Process for Coal.” International Journal of Mineral Processing 134: 97-110. |
| [12] | Journal, An International, Ajita Kumari, Alok Tripathy, and Venugopal Rayasam. 2020. “Performance Characterization and Misplacement Studies of Liquid - Solid Fluidized Bed Density Separator for Coal Beneficiation Using Taguchi- ANOVA Method.” Particulate Science and Technology 0(0): 1-13. |
| [13] | Kang, Hua, and He Zhang. 2022. “Enhanced Flotation Separation of Low-Rank Coal with a Mixed Collector: Experimental and Molecular Dynamics Simulation Study.” ACS Omega 7(38): 34239-48. |
| [14] | Katalambula, Hassan, and Rajender Gupta. 2009. “Low-Grade Coals: A Review of Some Prospective Upgrading Technologies.” Energy and Fuels 23(7): 3392-3405. |
| [15] | Kavalov, Boyan, and Stathis Peteves. 2007. 7 The Future of Coal The Future of Coal. |
| [16] | Li, Junguo, Guanghua Zhang, Ting Shang, and Junfeng Zhu. 2014. “Synthesis, Characterization and Application of a Dispersant Based on Rosin for Coal-Water Slurry.” International Journal of Mining Science and Technology 24(5): 695-99. |
| [17] | Polat, M, H Polat, and S Chander. 2003. “Physical and Chemical Interactions in Coal Flotation.” international journal of Mineral Processing 72: 199-213. |
| [18] | Ramudzwagi, M., N. Tshiongo-Makgwe, and W. Nheta. 2020. “Recent Developments in Beneficiation of Fine and Ultra-Fine Coal -Review Paper.” Journal of Cleaner Production 276: 122693. |
| [19] | Shen, Liang, and Huaifa Wang. 2016. “PROPERTIES OF FATTY ACID / DODECYLAMINE MIXTURES AND THEIR APPLICATION.” Physicochemical Problems of Mineral Processing 52(1): 303-16. |
| [20] | Sokolovic, Jovica, and Sanja Miskovic. 2018. “The Effect of Particle Size on Coal Flotation Kinetics : A Review.” physicochemical Problems of Mineral Processing 54(4): 1172-90. |
| [21] | State, Kogi, and Nigerian Defence Academy. 2025. “Quantitative Assessment of Heavy Metals Contamination in Nigerian Coal Using Instrumental Neutron Activation Analysis NIGERIAN JOURNAL OF PHYSICS.” Nigerian Journal of Physics 34(1): 13-20. |
| [22] | Tadesse, Solomon, Jean-pierre Milesi, and Yves Deschamps. 2003. “Geology and Mineral Potential of Ethiopi a : A Note on Geology and Mineral Map of Ethiopia.” Journal of African Earth Sciences 36: 273-313. |
| [23] | Thakur, Pramod. 2020. Coal Bed Methane: Theory and Applications CO2 Sequestration and Underground Coal Gasification with Horizontal Wells. 2nd ed. Elsevier Inc. |
| [24] | Wang, Xin, Rui Ding, Xinyu Cui, Yonghong Qin, Gan Cheng, George Abaka-Wood, and Enze Li. 2025. “New Insights for Improving Low-Rank Coal Flotation Performance via Tetrahydrofurfuryl Ester Collectors.” Minerals 15(1). |
| [25] | Wolela, Ahmed. 2007. “Fossil Fuel Energy Resources of Ethiopia: Coal Deposits.” International Journal of Coal Geology 72(3-4): 293-314. |
| [26] | Xia, Yangchao, Rui Zhang, Yijun Cao, Yaowen Xing, and Xiahui Gui. 2020. “Role of Molecular Simulation in Understanding the Mechanism of Low-Rank Coal Flotation: A Review.” Fuel 262(August): 116535. |
| [27] | Xing, Yaowen, Xiahui Gui, Yijun Cao, Dapeng Wang, and Haijun Zhang. 2017. “Clean Low-Rank-Coal Purification Technique Combining Cyclonic-Static Microbubble Flotation Column with Collector Emulsification.” Journal of Cleaner Production 153: 657-72. |
| [28] | Xing, Yaowen, Xiahui Gui, Yijun Cao, Yingwei Wang, Mengdi Xu, Dongyue Wang, and Chenwei Li. 2017. “Effect of Compound Collector and Blending Frother on Froth Stability and Fl Otation Performance of Oxidized Coal.” Powder Technology 305: 166-73. |
| [29] | Xing, Yaowen, Xiahui Gui, Jiongtian Liu, Yijun Cao, Yi Zhang, and Shulei Li. 2016. “Flotation Behavior of Hard-to-Separate and High-Ash Fine Coal.” Physicochemical Problems of Mineral Processing 52(2): 703-17. |
| [30] | Xing, Yaowen, Xuehong Xu, Xiahui Gui, Yijun Cao, and Mengdi Xu. 2017. “Effect of Kaolinite and Montmorillonite on Fine Coal Flotation.” Fuel 195: 284-89. |
| [31] | Yao, Ning, Jingting Liu, Xun Sun, Yan Liu, Songying Chen, and Guichao Wang. 2021. “A Rational Interpretation of the Role of Turbulence in Particle-Bubble Interactions.” Minerals 11(9): 1-12. |
| [32] | Zenebe, Basalfew, Argaw Ersedo, Desalegn Debelo, and Besifat Desalegn, Bekemaxe and Demberu. 2016. “Basic Geoscience Mapping Directorate Geology Geochemistry and Gravity Survey of Sede Area.” Ministry of Mines Petroleum and Natural Gas Geological Survey of Ethiopia Basic (October). |
| [33] | Zhu, Guangqing, Bo Zhang, Pengfei Zhao, Chenlong Duan, Yuemin Zhao, Zhenxing Zhang, Guanghui Yan, et al. 2019. “Upgrading Low-Quality Oil Shale Using High-Density Gas-Solid Fluidized Bed.” Fuel 252(March): 666-74. |
APA Style
Mulugeta, D., Mitku, E., Gebreyes, Z. (2025). Effects of Single and Mixed Collectors on Low-Grade Coal Flotation: In the Case of Gamo Zone Coal, Southern Ethiopia. International Journal of Oil, Gas and Coal Engineering, 13(4), 55-69. https://doi.org/10.11648/j.ogce.20251304.11
ACS Style
Mulugeta, D.; Mitku, E.; Gebreyes, Z. Effects of Single and Mixed Collectors on Low-Grade Coal Flotation: In the Case of Gamo Zone Coal, Southern Ethiopia. Int. J. Oil Gas Coal Eng. 2025, 13(4), 55-69. doi: 10.11648/j.ogce.20251304.11
@article{10.11648/j.ogce.20251304.11,
author = {Desta Mulugeta and Ewunetu Mitku and Zekarias Gebreyes},
title = {Effects of Single and Mixed Collectors on Low-Grade Coal Flotation: In the Case of Gamo Zone Coal, Southern Ethiopia
},
journal = {International Journal of Oil, Gas and Coal Engineering},
volume = {13},
number = {4},
pages = {55-69},
doi = {10.11648/j.ogce.20251304.11},
url = {https://doi.org/10.11648/j.ogce.20251304.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20251304.11},
abstract = {This study investigated the effectiveness of single and mixed collectors in enhancing the flotation efficiency of low-grade coal from the Gamo region of Ethiopia, focusing on recovery rates and ash content. The research aimed to address the challenges posed by high ash content and impurities in Ethiopian coal, which limit the industrial application. Through controlled laboratory experiments, the performance of single collectors (kerosene, diesel oil, and oleic acid) and mixed collectors in varying dosages was evaluated. The Finding revealed distinct performance characteristics among the collectors. Kerosene demonstrated higher recovery rates (33.7%) but moderate ash content (27.2%), while oleic acid prioritized purity (lowest ash content of 24.9%) at the expense of recovery (27.3%). Diesel oil showed intermediate results. Mixed collector formulations further highlighted the trade-off between recovery and ash content. For instance, the balanced triple-mixed collector C13 (kerosene, oleic acid, and diesel oil in equal parts) achieved a competitive recovery rate of 55.2% with acceptable ash levels (33.7%). In contrast, formulations with higher oleic acid content (C11) yielded the lowest ash content (32%) but reduced recovery (44%). The study underscored the inverse relationship between recovery and ash content, emphasizing the need for tailored collector blends based on specific industrial priorities. For yield-focused processes, Diesel-rich blends like C10 (56.3% recovery) are recommended, while purity-focused applications benefit from oleic acid-dominant mixtures like C11. The balanced C13 formulation emerged as a practical choice for scenarios requiring a middle ground.
},
year = {2025}
}
TY - JOUR T1 - Effects of Single and Mixed Collectors on Low-Grade Coal Flotation: In the Case of Gamo Zone Coal, Southern Ethiopia AU - Desta Mulugeta AU - Ewunetu Mitku AU - Zekarias Gebreyes Y1 - 2025/11/28 PY - 2025 N1 - https://doi.org/10.11648/j.ogce.20251304.11 DO - 10.11648/j.ogce.20251304.11 T2 - International Journal of Oil, Gas and Coal Engineering JF - International Journal of Oil, Gas and Coal Engineering JO - International Journal of Oil, Gas and Coal Engineering SP - 55 EP - 69 PB - Science Publishing Group SN - 2376-7677 UR - https://doi.org/10.11648/j.ogce.20251304.11 AB - This study investigated the effectiveness of single and mixed collectors in enhancing the flotation efficiency of low-grade coal from the Gamo region of Ethiopia, focusing on recovery rates and ash content. The research aimed to address the challenges posed by high ash content and impurities in Ethiopian coal, which limit the industrial application. Through controlled laboratory experiments, the performance of single collectors (kerosene, diesel oil, and oleic acid) and mixed collectors in varying dosages was evaluated. The Finding revealed distinct performance characteristics among the collectors. Kerosene demonstrated higher recovery rates (33.7%) but moderate ash content (27.2%), while oleic acid prioritized purity (lowest ash content of 24.9%) at the expense of recovery (27.3%). Diesel oil showed intermediate results. Mixed collector formulations further highlighted the trade-off between recovery and ash content. For instance, the balanced triple-mixed collector C13 (kerosene, oleic acid, and diesel oil in equal parts) achieved a competitive recovery rate of 55.2% with acceptable ash levels (33.7%). In contrast, formulations with higher oleic acid content (C11) yielded the lowest ash content (32%) but reduced recovery (44%). The study underscored the inverse relationship between recovery and ash content, emphasizing the need for tailored collector blends based on specific industrial priorities. For yield-focused processes, Diesel-rich blends like C10 (56.3% recovery) are recommended, while purity-focused applications benefit from oleic acid-dominant mixtures like C11. The balanced C13 formulation emerged as a practical choice for scenarios requiring a middle ground. VL - 13 IS - 4 ER -