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Preparation of Poly (N,N-diphenyl-4-amine) as the Cathode and Its Electrochemical Properties

Received: 9 August 2018     Published: 10 August 2018
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Abstract

Triphenylamine as well as its polymer have been applied in the fields of photoelectricity and energy storage. In this paper, the pyridine ring structure was introduced into the triphenylamine structure to successfully synthesize N, N-diphenyl-4-amine monomer (DPN), and the its single crystal was then cultured. And its homopolymer (PDPN) was further prepared by chemicaloxidation method. The obtained poly (triphenylamine) derivative-PDPN was used as cathode material to study its electrochemical and battery performance. As the result, the chemical structure of the monomer was confirmed by NMR, MS and single crstal analysis. And the chemical structure of PDPN was confirmed by infrared spectroscopy and ultraviolet spectroscopy. Furthermore, the battery performance test shows that PDPN electrode has two obvious voltage platforms in the voltage range of 4.1-4.3 V and 1.5-1.8 V, in which the initial discharge specific capacity was 92.3 mAh·g-1. After 50 cycles, its discharge specific capacity decreased from 92.3 mAh·g-1 to 73.2 mAh·g-1 with about 20.7% capacity loss.

Published in Science Discovery (Volume 6, Issue 4)
DOI 10.11648/j.sd.20180604.14
Page(s) 249-256
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Polytriphenylamine, Lithium Battery, Organic Cathode, Electrochemical Propeerties

References
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Cite This Article
  • APA Style

    Chang Su, Bing Han, Yue Sun, Guosheng Wang, Lihuan Xu. (2018). Preparation of Poly (N,N-diphenyl-4-amine) as the Cathode and Its Electrochemical Properties. Science Discovery, 6(4), 249-256. https://doi.org/10.11648/j.sd.20180604.14

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    ACS Style

    Chang Su; Bing Han; Yue Sun; Guosheng Wang; Lihuan Xu. Preparation of Poly (N,N-diphenyl-4-amine) as the Cathode and Its Electrochemical Properties. Sci. Discov. 2018, 6(4), 249-256. doi: 10.11648/j.sd.20180604.14

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    AMA Style

    Chang Su, Bing Han, Yue Sun, Guosheng Wang, Lihuan Xu. Preparation of Poly (N,N-diphenyl-4-amine) as the Cathode and Its Electrochemical Properties. Sci Discov. 2018;6(4):249-256. doi: 10.11648/j.sd.20180604.14

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  • @article{10.11648/j.sd.20180604.14,
      author = {Chang Su and Bing Han and Yue Sun and Guosheng Wang and Lihuan Xu},
      title = {Preparation of Poly (N,N-diphenyl-4-amine) as the Cathode and Its Electrochemical Properties},
      journal = {Science Discovery},
      volume = {6},
      number = {4},
      pages = {249-256},
      doi = {10.11648/j.sd.20180604.14},
      url = {https://doi.org/10.11648/j.sd.20180604.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20180604.14},
      abstract = {Triphenylamine as well as its polymer have been applied in the fields of photoelectricity and energy storage. In this paper, the pyridine ring structure was introduced into the triphenylamine structure to successfully synthesize N, N-diphenyl-4-amine monomer (DPN), and the its single crystal was then cultured. And its homopolymer (PDPN) was further prepared by chemicaloxidation method. The obtained poly (triphenylamine) derivative-PDPN was used as cathode material to study its electrochemical and battery performance. As the result, the chemical structure of the monomer was confirmed by NMR, MS and single crstal analysis. And the chemical structure of PDPN was confirmed by infrared spectroscopy and ultraviolet spectroscopy. Furthermore, the battery performance test shows that PDPN electrode has two obvious voltage platforms in the voltage range of 4.1-4.3 V and 1.5-1.8 V, in which the initial discharge specific capacity was 92.3 mAh·g-1. After 50 cycles, its discharge specific capacity decreased from 92.3 mAh·g-1 to 73.2 mAh·g-1 with about 20.7% capacity loss.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Preparation of Poly (N,N-diphenyl-4-amine) as the Cathode and Its Electrochemical Properties
    AU  - Chang Su
    AU  - Bing Han
    AU  - Yue Sun
    AU  - Guosheng Wang
    AU  - Lihuan Xu
    Y1  - 2018/08/10
    PY  - 2018
    N1  - https://doi.org/10.11648/j.sd.20180604.14
    DO  - 10.11648/j.sd.20180604.14
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 249
    EP  - 256
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20180604.14
    AB  - Triphenylamine as well as its polymer have been applied in the fields of photoelectricity and energy storage. In this paper, the pyridine ring structure was introduced into the triphenylamine structure to successfully synthesize N, N-diphenyl-4-amine monomer (DPN), and the its single crystal was then cultured. And its homopolymer (PDPN) was further prepared by chemicaloxidation method. The obtained poly (triphenylamine) derivative-PDPN was used as cathode material to study its electrochemical and battery performance. As the result, the chemical structure of the monomer was confirmed by NMR, MS and single crstal analysis. And the chemical structure of PDPN was confirmed by infrared spectroscopy and ultraviolet spectroscopy. Furthermore, the battery performance test shows that PDPN electrode has two obvious voltage platforms in the voltage range of 4.1-4.3 V and 1.5-1.8 V, in which the initial discharge specific capacity was 92.3 mAh·g-1. After 50 cycles, its discharge specific capacity decreased from 92.3 mAh·g-1 to 73.2 mAh·g-1 with about 20.7% capacity loss.
    VL  - 6
    IS  - 4
    ER  - 

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Author Information
  • College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China

  • College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China

  • College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China

  • College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China

  • College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang, China

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