A new asymmetric bidentate Schiff base ligand was synthesized from a condensation reaction between 2,4-dichlorobenzaldehyde (C7H4Cl2O) and 1,3-pentanediamine (C5H14N2). A cadmium complex was prepared by adding Cd(II) iodide dissolved in methanol to a methanolic solution of the Schiff base ligand, in a ratio of 1:1. The ligand was characterized by elemental, spectroscopic (IR, 1H NMR), and thermogravimetric analyses. The ligand structure, thermally very stable, is revealed to be bidentate with two potential N-donor sites. The crystal structure of the Schiff base was elucidated by X-ray diffraction analysis. Compound crystallizes in a monoclinic system with a space group P21/n and a number of units per unit cell Z = 4. The unit cell parameters are: a =7.3885(2), b =16.9332 (4), c = 15.5624(4), and β = 90.4306(10). In the asymmetric unit of the ligand, the benzene rings C08/C10/C09/C11/C21/C17 and C20/C15/C13/C18/C22/C24 are in trans position with the aliphatic group with respect to the bonds (C07-N05) and (C19-N06), respectively. In addition, these two aromatic rings are located in two different planes, forming an angle of 3.60º between them, given that the dihedral angle between the ring C08/C10/C09/C11/C21/C17 and the aliphatic group N05-N06 is 67.49º. The spectroscopic data of the complex reveals a mononuclear complex where the Cd(II) ion is housed in a N2I2 coordination site with a slightly distorted tetrahedral geometry. The conductance data indicate that the complex is a neutral electrolyte.
| Published in | Science Journal of Chemistry (Volume 12, Issue 6) |
| DOI | 10.11648/j.sjc.20241206.13 |
| Page(s) | 135-143 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Copyright © The Author(s), 2024. Published by Science Publishing Group |
Schiff Base, Cadmium, Ligand, Complex, Crystal Structure
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APA Style
Diop, A., Diop, T., Ndoye, D., Seye, D., Tinnemans, P., et al. (2024). Synthesis, Spectroscopic Studies, Thermal Stability and Crystal Structure of New Bidentate Schiff Base and Its Cadmium Complex. Science Journal of Chemistry, 12(6), 135-143. https://doi.org/10.11648/j.sjc.20241206.13
ACS Style
Diop, A.; Diop, T.; Ndoye, D.; Seye, D.; Tinnemans, P., et al. Synthesis, Spectroscopic Studies, Thermal Stability and Crystal Structure of New Bidentate Schiff Base and Its Cadmium Complex. Sci. J. Chem. 2024, 12(6), 135-143. doi: 10.11648/j.sjc.20241206.13
AMA Style
Diop A, Diop T, Ndoye D, Seye D, Tinnemans P, et al. Synthesis, Spectroscopic Studies, Thermal Stability and Crystal Structure of New Bidentate Schiff Base and Its Cadmium Complex. Sci J Chem. 2024;12(6):135-143. doi: 10.11648/j.sjc.20241206.13
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Download@article{10.11648/j.sjc.20241206.13,
author = {Aboubacar Diop and Tidiane Diop and Daouda Ndoye and Dame Seye and Paul Tinnemans and Cheikh Abdoul Khadir Diop},
title = {Synthesis, Spectroscopic Studies, Thermal Stability and Crystal Structure of New Bidentate Schiff Base and Its Cadmium Complex
},
journal = {Science Journal of Chemistry},
volume = {12},
number = {6},
pages = {135-143},
doi = {10.11648/j.sjc.20241206.13},
url = {https://doi.org/10.11648/j.sjc.20241206.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20241206.13},
abstract = {A new asymmetric bidentate Schiff base ligand was synthesized from a condensation reaction between 2,4-dichlorobenzaldehyde (C7H4Cl2O) and 1,3-pentanediamine (C5H14N2). A cadmium complex was prepared by adding Cd(II) iodide dissolved in methanol to a methanolic solution of the Schiff base ligand, in a ratio of 1:1. The ligand was characterized by elemental, spectroscopic (IR, 1H NMR), and thermogravimetric analyses. The ligand structure, thermally very stable, is revealed to be bidentate with two potential N-donor sites. The crystal structure of the Schiff base was elucidated by X-ray diffraction analysis. Compound crystallizes in a monoclinic system with a space group P21/n and a number of units per unit cell Z = 4. The unit cell parameters are: a =7.3885(2), b =16.9332 (4), c = 15.5624(4), and β = 90.4306(10). In the asymmetric unit of the ligand, the benzene rings C08/C10/C09/C11/C21/C17 and C20/C15/C13/C18/C22/C24 are in trans position with the aliphatic group with respect to the bonds (C07-N05) and (C19-N06), respectively. In addition, these two aromatic rings are located in two different planes, forming an angle of 3.60º between them, given that the dihedral angle between the ring C08/C10/C09/C11/C21/C17 and the aliphatic group N05-N06 is 67.49º. The spectroscopic data of the complex reveals a mononuclear complex where the Cd(II) ion is housed in a N2I2 coordination site with a slightly distorted tetrahedral geometry. The conductance data indicate that the complex is a neutral electrolyte.
},
year = {2024}
}
TY - JOUR T1 - Synthesis, Spectroscopic Studies, Thermal Stability and Crystal Structure of New Bidentate Schiff Base and Its Cadmium Complex AU - Aboubacar Diop AU - Tidiane Diop AU - Daouda Ndoye AU - Dame Seye AU - Paul Tinnemans AU - Cheikh Abdoul Khadir Diop Y1 - 2024/11/26 PY - 2024 N1 - https://doi.org/10.11648/j.sjc.20241206.13 DO - 10.11648/j.sjc.20241206.13 T2 - Science Journal of Chemistry JF - Science Journal of Chemistry JO - Science Journal of Chemistry SP - 135 EP - 143 PB - Science Publishing Group SN - 2330-099X UR - https://doi.org/10.11648/j.sjc.20241206.13 AB - A new asymmetric bidentate Schiff base ligand was synthesized from a condensation reaction between 2,4-dichlorobenzaldehyde (C7H4Cl2O) and 1,3-pentanediamine (C5H14N2). A cadmium complex was prepared by adding Cd(II) iodide dissolved in methanol to a methanolic solution of the Schiff base ligand, in a ratio of 1:1. The ligand was characterized by elemental, spectroscopic (IR, 1H NMR), and thermogravimetric analyses. The ligand structure, thermally very stable, is revealed to be bidentate with two potential N-donor sites. The crystal structure of the Schiff base was elucidated by X-ray diffraction analysis. Compound crystallizes in a monoclinic system with a space group P21/n and a number of units per unit cell Z = 4. The unit cell parameters are: a =7.3885(2), b =16.9332 (4), c = 15.5624(4), and β = 90.4306(10). In the asymmetric unit of the ligand, the benzene rings C08/C10/C09/C11/C21/C17 and C20/C15/C13/C18/C22/C24 are in trans position with the aliphatic group with respect to the bonds (C07-N05) and (C19-N06), respectively. In addition, these two aromatic rings are located in two different planes, forming an angle of 3.60º between them, given that the dihedral angle between the ring C08/C10/C09/C11/C21/C17 and the aliphatic group N05-N06 is 67.49º. The spectroscopic data of the complex reveals a mononuclear complex where the Cd(II) ion is housed in a N2I2 coordination site with a slightly distorted tetrahedral geometry. The conductance data indicate that the complex is a neutral electrolyte. VL - 12 IS - 6 ER -
Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
Department of Physics-Chemistry, UFR Science and Technology, Iba Der Thiam University, Thies, Senegal
Institute for Molecules and Materials (IMM) Solid State Chemistry, Faculty of Science Radboud University, Nijmegen, Netherlands
Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal
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