Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples

Almojtaba AbdAlkhalig Ahmed Bakheet; Xiashi Zhu

doi:doi:10.11648/j.ijbc.20170201.15

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Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples

Almojtaba AbdAlkhalig Ahmed Bakheet, Xiashi Zhu

Published in International Journal of Bioorganic Chemistry (Volume 2, Issue 1)

Received: 26 January 2017 Accepted: 13 February 2017 Published: 2 March 2017

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Abstract

Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.

Published in	International Journal of Bioorganic Chemistry (Volume 2, Issue 1)
DOI	10.11648/j.ijbc.20170201.15
Page(s)	30-35
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Allura Red, Ionic Liquids-β-Cyclodextrin Polymer, Solid-Phase Extraction, UV-visible Spectrophotometry

References

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APA Style

Almojtaba AbdAlkhalig Ahmed Bakheet, Xiashi Zhu. (2017). Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. International Journal of Bioorganic Chemistry, 2(1), 30-35. https://doi.org/10.11648/j.ijbc.20170201.15

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ACS Style

Almojtaba AbdAlkhalig Ahmed Bakheet; Xiashi Zhu. Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. Int. J. Bioorg. Chem. 2017, 2(1), 30-35. doi: 10.11648/j.ijbc.20170201.15

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AMA Style

Almojtaba AbdAlkhalig Ahmed Bakheet, Xiashi Zhu. Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. Int J Bioorg Chem. 2017;2(1):30-35. doi: 10.11648/j.ijbc.20170201.15

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@article{10.11648/j.ijbc.20170201.15,
  author = {Almojtaba AbdAlkhalig Ahmed Bakheet and Xiashi Zhu},
  title = {Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples},
  journal = {International Journal of Bioorganic Chemistry},
  volume = {2},
  number = {1},
  pages = {30-35},
  doi = {10.11648/j.ijbc.20170201.15},
  url = {https://doi.org/10.11648/j.ijbc.20170201.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbc.20170201.15},
  abstract = {Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.},
 year = {2017}
}

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TY  - JOUR
T1  - Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples
AU  - Almojtaba AbdAlkhalig Ahmed Bakheet
AU  - Xiashi Zhu
Y1  - 2017/03/02
PY  - 2017
N1  - https://doi.org/10.11648/j.ijbc.20170201.15
DO  - 10.11648/j.ijbc.20170201.15
T2  - International Journal of Bioorganic Chemistry
JF  - International Journal of Bioorganic Chemistry
JO  - International Journal of Bioorganic Chemistry
SP  - 30
EP  - 35
PB  - Science Publishing Group
SN  - 2578-9392
UR  - https://doi.org/10.11648/j.ijbc.20170201.15
AB  - Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.
VL  - 2
IS  - 1
ER  -

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Author Information

Almojtaba AbdAlkhalig Ahmed Bakheet

College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, PR China
Xiashi Zhu

College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, PR China

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Plain Text BibTeX RIS

APA Style

Almojtaba AbdAlkhalig Ahmed Bakheet, Xiashi Zhu. (2017). Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. International Journal of Bioorganic Chemistry, 2(1), 30-35. https://doi.org/10.11648/j.ijbc.20170201.15

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ACS Style

Almojtaba AbdAlkhalig Ahmed Bakheet; Xiashi Zhu. Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. Int. J. Bioorg. Chem. 2017, 2(1), 30-35. doi: 10.11648/j.ijbc.20170201.15

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AMA Style

Almojtaba AbdAlkhalig Ahmed Bakheet, Xiashi Zhu. Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples. Int J Bioorg Chem. 2017;2(1):30-35. doi: 10.11648/j.ijbc.20170201.15

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@article{10.11648/j.ijbc.20170201.15,
  author = {Almojtaba AbdAlkhalig Ahmed Bakheet and Xiashi Zhu},
  title = {Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples},
  journal = {International Journal of Bioorganic Chemistry},
  volume = {2},
  number = {1},
  pages = {30-35},
  doi = {10.11648/j.ijbc.20170201.15},
  url = {https://doi.org/10.11648/j.ijbc.20170201.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbc.20170201.15},
  abstract = {Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Ionic Liquids-β-Cyclodextrin Polymer for Separation/Analysis Allura Red in Food Samples
AU  - Almojtaba AbdAlkhalig Ahmed Bakheet
AU  - Xiashi Zhu
Y1  - 2017/03/02
PY  - 2017
N1  - https://doi.org/10.11648/j.ijbc.20170201.15
DO  - 10.11648/j.ijbc.20170201.15
T2  - International Journal of Bioorganic Chemistry
JF  - International Journal of Bioorganic Chemistry
JO  - International Journal of Bioorganic Chemistry
SP  - 30
EP  - 35
PB  - Science Publishing Group
SN  - 2578-9392
UR  - https://doi.org/10.11648/j.ijbc.20170201.15
AB  - Ionic liquids β-cyclodextrin polymer (mono-6-deoxy-6-(1-ethyl-imidazolium)-β-cyclodextrin iodide polymer, ILs-β-CDCP) was synthesized. A novel method based on ILs-β-CDCP solid phase extraction coupled with UV-visible spectrophotometry for the preconcentration / separation allura red (AR) was investigated. The results was shown that AR was adsorbed on ILs-β-CDCP and eluted with sodium dodecyl sulfate (SDS) (1%) rapidly. Under the optimum conditions, the preconcentration factor for AR was 27. The linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.10-9.00 μg/mL, 5.2 μg/L, 0.9987 and 3.10% (n=3, c=4.00 μg/mL), respectively. The adsorption mechanism of ILs-β-CDCP on AR was studied through the FTIR analysis and the inclusion constant of ILs-β-CDCP-AR. This proposed method has been successfully applied to the determination of AR in food samples.
VL  - 2
IS  - 1
ER  -

Copy | Download