The present research looked at a passivation method for polished nitinol based implant and stent component after a standard heat setting treatment. Passivation of heat-treated samples in a nitric acid solution was followed by a series of corrosion tests, surface examination, and chemical analysis. The enhancement in corrosion resistance is suggested by a chemical study of passivation solutions. After prolonged immersion in saline solution, the enhanced corrosion resistance is maintained. The chemical treatment leads to a protective oxide layer that is less likely to chemically react with air and cause corrosion. On an implant surface that has undergone chemical cleaning, the chemical treatment that will hasten the creation of the passive coating must be performed. The surfaces of the passivated components must be chemically clean, and a visual inspection must reveal no etching, pitting, or freezing. The chemical passivation process stops the surface's corrosion from its path. A passivation treatment using 10 - 60% nitric acid at 80 - 90°C for 20 min has been successfully applied to mechanically polished nitinol, after a typical shape setting heat treatment. The process undergoes till the color of the nitinol implant changes from violet blue to polished white.
Published in | World Journal of Applied Chemistry (Volume 7, Issue 3) |
DOI | 10.11648/j.wjac.20220703.12 |
Page(s) | 73-78 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2022. Published by Science Publishing Group |
Chemical Passivation, Nitinol Stent, Nitric Acid Solution
[1] | Athos F. A., Marcos V. F. Ferreira, Marcos D. V. Felisberto, Dalila C. Sicupira, Leandro A. Santos. Corrosion resistance of a super elastic NiTi alloy coated with graphene–based coatings, Progress in Organic Coatings. 2022; 165. |
[2] | Ayyagari A., Hasannaeimi V., Grewal H. S., Arora H., and Mukherjee S. Corrosion. Erosion and Wear Behavior of complex concentrated Alloys: A Review. Metals. 2018; 8 (8): 603. https://doi.org/10.3390/met |
[3] | Beck stefan W. Passivation studies of weathered and fresh sulfidic Rock. University of Nevada, Reno Proquest Dissertations. 2003. |
[4] | Behera Ajit. Smart applications of NiTi shape memory alloy in biomedical industries, Nickel-Titanium Smart Hybrid Materials. 2022; 327-354. |
[5] | Brien B. O., Carroll W. M., and Kelly M. J. Passivation of nitinol wire for vascular implants - a demostration of the benefits. 2002; 23 (8): 1739-1748. doi: 10.1016/s0142-9612(01)00299–x. |
[6] | Briglin S. M., Gao T., and Lewis N. S. Detection of organic mercaptan vapors using Thin films of Alkalymine - Passivated Gold Nanocrystals. Langmuir. 2004; 20 (2): 299-305. |
[7] | Browne M, Gregson P. J., and West R. H. Characterization of titanium alloy implant surfaces with improved dissolution resistance. J Mater Sci Mater Med. 1996; 7: 323-329. |
[8] | Bruce G. Pound. The use of electrochemical techniques to evaluate the corrosion performance of metallic biomedical materials and devices. Journal of Biomedical Materials Research Part B: Applied Biomaterials. 2018; 107 (4): 1189-1198. |
[9] | Chan C. M., Trigwell S., and Duerig T. Oxidation of an NiTi alloy. Surf Interface Anal. 1990; 15: 349-354. |
[10] | Eliaz N., and Nissan O. Innovative processes for electropolishing of medical devices made of stainless steels. Journal of Biomedical Materials Research. 2007; 83 (A): 546-557. |
[11] | Fan Sun, Laurence Jordan, Valerie Albin, Virginie Lair, Armelle Ringuede and Frederic Prima. On the High Sensitivity of Corrosion Resistance of NiTi Stents with Respect to Inclusions: An Experimental Evidence. ACS Omega. 2020; 5 (6): 3073-3079. |
[12] | Gan J. A., and Berndt C. C. Plasma surface modification of metallic biomaterials. Surface Coating and Modification of Metallic Biomaterials. 2015; 103-157. |
[13] | Hanrath Tobias and Korgel B. A. Chemical Surface Passivation of Ge Nanowires. Journal of the American Chemical Society. 2004; 126 (47): 15466-15472. |
[14] | Hodges B. C., Cates E. L., and Kim Jae - Hong. Challenges and Prospects of Advanced Oxidation water treatment processes using catalytic nanomaterials. Nature Nanotechnology. 2018; 13: 642-650. |
[15] | J. Dong, M. Pacella, Y. and Liu L. Z. Surface engineering and the application of laser-based processes to stents - A review of the latest development, Bioactive Materials. 2022; 10: 159-184. |
[16] | Liu Yue, Chen Junghuei, Teplyakov, and Andrew V. (2012). Chemical Passivation Processes for Biofunctionalization Schemes on Semiconductor Surfaces. Langmuir. 2012; 28 (44): 15521-15528. |
[17] | Melisa Saugo, Daniel O. F., and Silvana B. S. Low-Voltage Polarization in AOT Solution to Enhance the Corrosion Resistance of Nitinol, Journal of Materials Engineering and Performance. 2021; 30 (3): 1816-1824. |
[18] | Montero O. C., Lopez H., and Salinas R. A. Effect of compressive straining on corrosion resistance of a shape memory Ni–Ti alloy in ringer’s solution. J Biomed Mater Res. 1996; 32: 583–591. |
[19] | Niska R. H., Constant A. P., Witt T., and Gregory O. J. Chemical vapor deposition of alpha aluminum oxide for high temperature aerospace sensors. Journal of Vacuum Science and Technology A. 2000; 18: 1653. |
[20] | Ogle Kevin. Atomic Emission Spectroelectrochemistry: Real Time Rate Measurement of Dissolution, corrosion and passivation. Corrosion: The Journal of Science and Engineering. 2019; 75 (12): 1398-1419. |
[21] | Pan T., and Lu Yang. Quantum chemistry Based studying of Rebar passivation in Alkaline concrete environment. International Journal of Electrochemical Science. 2011; 6: 4967-4983. |
[22] | Samarasinghe S., Hui M., Ekanayake C., Martin D., and Saha Tapan. Investigating passivator effectiveness for preventing silver sulfide corrosion in power transformer on load trape changers. IEEE: Transactions on Dielectrics and Electrical Insulation. Conference 2020; 27 (5): 1761-1768. |
[23] | Shari N. R., Kumar p., and Christopher L. The role of surface oxide thickness and structure on the corrosion and nickel elution behavior of nitinol biomedical implants, Journal of Biomedical Materials Research Part B: Applied Biomaterials. 2021; 9: 1334-1343. |
[24] | Srinidhi Nagaraja and Alan R. P. Corrosion resistance of a Nitinol ocular microstent: Implications on biocompatibility, Journal of Biomedical Materials Research Part B: Applied Biomaterials. 2020; 108 (6): 2681-2690. 10.1002/jbm.b.34599. |
[25] | Thierry B., Tabrizian M., Savadogo O., and Yahia L. H. Effects of sterilization processes on NiTi alloy: surface characterization. J Biomed Mater Res. 2000; 49: 88-98. |
[26] | Trepanier C, Tabrizian M, Yahia L. H., Bilodeau L., and Piron D. L. Effect of modification of oxide layer on NiTi stent corrosion resistance. J Biomed Mater Res (Appl Biomater). 1998; 43: 433-440. |
[27] | Wever D. J., Veldhuizen A. G., de Vries J, Busscher H. J., Uges DRA and van Horn JR. Electrochemical and surface characterization of a nickel–titanium alloy. Biomaterials. 1998; 19: 761-769. |
APA Style
Dr. Pramod Kumar Minocha, Kothwala Deveshkumar Mahendralal, Durani Mohamadovesh Mohamadyasin, Tamboli Prasadkumar Sunilbhai. (2022). Effect of Chemical Passivation on Nitinol Based Implant. World Journal of Applied Chemistry, 7(3), 73-78. https://doi.org/10.11648/j.wjac.20220703.12
ACS Style
Dr. Pramod Kumar Minocha; Kothwala Deveshkumar Mahendralal; Durani Mohamadovesh Mohamadyasin; Tamboli Prasadkumar Sunilbhai. Effect of Chemical Passivation on Nitinol Based Implant. World J. Appl. Chem. 2022, 7(3), 73-78. doi: 10.11648/j.wjac.20220703.12
@article{10.11648/j.wjac.20220703.12, author = {Dr. Pramod Kumar Minocha and Kothwala Deveshkumar Mahendralal and Durani Mohamadovesh Mohamadyasin and Tamboli Prasadkumar Sunilbhai}, title = {Effect of Chemical Passivation on Nitinol Based Implant}, journal = {World Journal of Applied Chemistry}, volume = {7}, number = {3}, pages = {73-78}, doi = {10.11648/j.wjac.20220703.12}, url = {https://doi.org/10.11648/j.wjac.20220703.12}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20220703.12}, abstract = {The present research looked at a passivation method for polished nitinol based implant and stent component after a standard heat setting treatment. Passivation of heat-treated samples in a nitric acid solution was followed by a series of corrosion tests, surface examination, and chemical analysis. The enhancement in corrosion resistance is suggested by a chemical study of passivation solutions. After prolonged immersion in saline solution, the enhanced corrosion resistance is maintained. The chemical treatment leads to a protective oxide layer that is less likely to chemically react with air and cause corrosion. On an implant surface that has undergone chemical cleaning, the chemical treatment that will hasten the creation of the passive coating must be performed. The surfaces of the passivated components must be chemically clean, and a visual inspection must reveal no etching, pitting, or freezing. The chemical passivation process stops the surface's corrosion from its path. A passivation treatment using 10 - 60% nitric acid at 80 - 90°C for 20 min has been successfully applied to mechanically polished nitinol, after a typical shape setting heat treatment. The process undergoes till the color of the nitinol implant changes from violet blue to polished white.}, year = {2022} }
TY - JOUR T1 - Effect of Chemical Passivation on Nitinol Based Implant AU - Dr. Pramod Kumar Minocha AU - Kothwala Deveshkumar Mahendralal AU - Durani Mohamadovesh Mohamadyasin AU - Tamboli Prasadkumar Sunilbhai Y1 - 2022/08/05 PY - 2022 N1 - https://doi.org/10.11648/j.wjac.20220703.12 DO - 10.11648/j.wjac.20220703.12 T2 - World Journal of Applied Chemistry JF - World Journal of Applied Chemistry JO - World Journal of Applied Chemistry SP - 73 EP - 78 PB - Science Publishing Group SN - 2637-5982 UR - https://doi.org/10.11648/j.wjac.20220703.12 AB - The present research looked at a passivation method for polished nitinol based implant and stent component after a standard heat setting treatment. Passivation of heat-treated samples in a nitric acid solution was followed by a series of corrosion tests, surface examination, and chemical analysis. The enhancement in corrosion resistance is suggested by a chemical study of passivation solutions. After prolonged immersion in saline solution, the enhanced corrosion resistance is maintained. The chemical treatment leads to a protective oxide layer that is less likely to chemically react with air and cause corrosion. On an implant surface that has undergone chemical cleaning, the chemical treatment that will hasten the creation of the passive coating must be performed. The surfaces of the passivated components must be chemically clean, and a visual inspection must reveal no etching, pitting, or freezing. The chemical passivation process stops the surface's corrosion from its path. A passivation treatment using 10 - 60% nitric acid at 80 - 90°C for 20 min has been successfully applied to mechanically polished nitinol, after a typical shape setting heat treatment. The process undergoes till the color of the nitinol implant changes from violet blue to polished white. VL - 7 IS - 3 ER -